Chapter 20: Q14P (page 525)
Calculate the power per unit area (the exitance, W/m2) radiating from a blackbody at 77 K (liquid nitrogen temperature) and at 298 K (room temperature).
Short Answer
The value of Planck distribution at 77k and 298k
Chapter 20: Q14P (page 525)
Calculate the power per unit area (the exitance, W/m2) radiating from a blackbody at 77 K (liquid nitrogen temperature) and at 298 K (room temperature).
The value of Planck distribution at 77k and 298k
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Get started for freeIn Figure 20-35, the relative detection limit is 37 after 1sof signal averaging, 12.5 after 10s, and 5.6 after 40 sof signal averaging. Based on the value of 37 at 1 s, what are the expected detection limits at 10 sand 40 sin an ideal experiment?
What level of stray light gives an absorbance error of 0.01 at an absorbance of 2? That is, what value of Sgives an apparent absorbance of 1.99?
Results of an electrochemical experiment are shown in the figure. In each case, a voltage is applied between two electrodes at timeand the absorbance of a solution decreases until the voltage is stepped back to its initial value at time. The upper traces show the average results for 100,300, and 1000 repetitions of the experiment. The measured signal-to-rms noise ratio in the upper trace is 60.0. Predict the signal-to-noise ratios expected for 300 cycles, 100 cycles, and 1 cycle and compare your answers with the observed values in the figure.
(a) The true absorbance of a sample is 1.500, but stray light reaches the detector. Find the apparent transmittance and apparent absorbance of the sample. (b) How much stray light can be tolerated if the absorbance error is not to exceedat a true absorbance of? (c) A research-quality spectrophotometer has a stray light level of ,at. What will be the maximum absorbance error for a sample with a true absorbance of 2? Of 3?
Consider a reflection grating operating with an incident angle of 408 in Figure 20-7. (a) How many lines per centimeter should be etched in the grating if the first-order diffraction angle for 600 nm (visible) light is to be 2308? (b) Answer the same question for 1 000 cm21 (infrared) light.
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