Chapter 20: Q10P (page 525)
Show that a grating with 103 grooves/cm provides a dispersion of 5.88 per mm of wavelength if n 5 1 and f 5 108 in Equation 20-4.
Chapter 20: Q10P (page 525)
Show that a grating with 103 grooves/cm provides a dispersion of 5.88 per mm of wavelength if n 5 1 and f 5 108 in Equation 20-4.
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Get started for freeIn Figure 20-35, the relative detection limit is 37 after 1sof signal averaging, 12.5 after 10s, and 5.6 after 40 sof signal averaging. Based on the value of 37 at 1 s, what are the expected detection limits at 10 sand 40 sin an ideal experiment?
Explain why the transmission spectrum is calculated from the quotient (sample transform) M(background transform) instead of the difference (sample transform) - (background transform).
Here is an extremely sensitive method for measuring nitrite () down to in natural waters. The water sample is treated with sulfanilamide and N-(1-naphthylethylenediamine) in acid solution to produce a colored product with a molar absorptivity of at 540 nm. The colored solution is pumped into a 4.5-meter-long, coiled Teflon tube whose fluorocarbon wall has a refractive index of 1.29. The aqueous solution inside the tube has a refractive index near 1.33. The colored solution is pumped through the coiled tube. An optical fiber delivers white light into one end of the tube, and an optical fiber at the other end leads to a polychromator and detector.
(a) Explain the purpose of the coiled Teflon tube and explain how it functions.
(b) What is the critical angle of incidence for total internal reflection at the Teflon/water interface?
(c) What is the predicted absorbance of a solution of colored reagent?
Calculate the power per unit area (the exitance, W/m2) radiating from a blackbody at 77 K (liquid nitrogen temperature) and at 298 K (room temperature).
20-D. The table shows signal-to-noise ratios recorded in a nuclear magnetic resonance experiment. Construct graphs of
(a) signal-to-noise ratio versus n and
(b) signal-to-noise ratio versus , where n is the number of scans. Draw error bars corresponding to the standard deviation at each point. Is the signal-to-noise ratio proportional to ? Find the 95% confidence interval for each row of the table.
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