Chapter 20: Q1 TY (page 500)
What level of stray light gives an absorbance error of 0.01 at an absorbance of 2? That is, what value of Sgives an apparent absorbance of 1.99?
Short Answer
The apparent transmittance equation is as follows:
Chapter 20: Q1 TY (page 500)
What level of stray light gives an absorbance error of 0.01 at an absorbance of 2? That is, what value of Sgives an apparent absorbance of 1.99?
The apparent transmittance equation is as follows:
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(a) In the cavity ring-down measurement at the opening of this chapter, absorbance is given by whereis the length of the triangular path in the cavity, Cis the speed of light, Tis the ring-down lifetime with sample in the cavity, and is the ring-down lifetime with no sample in the cavity. Ring-down lifetime is obtained by fitting the observed ring-down signal intensityto an exponential decay of the form , whereis the initial intensity and t is time. A measurement ofis made at a wavelength absorbed by the molecule. The ring-down lifetime for 21.0-cm-1 along empty cavity is andfor a cavity containing.role="math" localid="1664865078479" Find the absorbance ofat this wavelength.
(b) The ring-down spectrum below arises from and from of methane in outdoor air at 0.13. The spectrum arises from individual rotational transitions of the ground vibrational state to a second excited C-H)vibrational state of the molecule. (i) Explain what quantity is plotted on the ordinate ( Y-axis). (ii) The peak foris at. What is the wavelength of this peak in? What is the name of the spectral region where this peak is found?
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Would you use a tungsten or a deuterium lamp as a source of 300-nm radiation? What kind of lamp provides radiation at 4-mm wavelength?
(a) The true absorbance of a sample is 1.500, but stray light reaches the detector. Find the apparent transmittance and apparent absorbance of the sample. (b) How much stray light can be tolerated if the absorbance error is not to exceedat a true absorbance of? (c) A research-quality spectrophotometer has a stray light level of ,at. What will be the maximum absorbance error for a sample with a true absorbance of 2? Of 3?
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