Warning: foreach() argument must be of type array|object, bool given in /var/www/html/web/app/themes/studypress-core-theme/template-parts/header/mobile-offcanvas.php on line 20

Here is a use objective for a chemical analysis to be performed at a drinking water purification plant: "Data and results collected quarterly shall will be used to determine whether the concentrations of haloacetates in the treated water demonstrate compliance with the levels set by the Stage 1 Disinfection By-products Rule using Method 552.2"(a specification that sets precision, accuracy, and other requirements).

Which one of the following questions best summarizes the meaning of the use objective?

(i) Are haloacetate concentrations known within specified precision and accuracy?

(ii) Are thehaloacetates detectable in the water?

(iii) Dothehaloacetate concentrations exceed the regulatory limit?

Short Answer

Expert verified

Amongst statements i, ii, and iii, statement iii is the right answer.

Step by step solution

01

Definition of chemical analysis

Chemical analysis is the study of a substance's chemical composition and structure. More broadly, it can be thought of as the collection of all procedures for obtaining precise chemical data.

02

Reason for right answer

Statement 3 is the right answer.

The purpose of the analysis is to check if concentrations do not go beyond the levels set by a definite rule.

03

Reason for wrong answer

Statements 1 and 2 are wrong because the queries about precision, and accuracy, and detectability in water are irrelevant to the data collection


Conclusion

The question above explained how the data and results collected quarterly will be used to determine whether the concentrations of haloacetates in the treated water are in compliance with the statutory levels..

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Blind Samples: Interpreting Statistics-- The U.S. Department of Agriculture provided homogenized beef baby food samples to three labs for analysis.4Results from the labs agreed well for protein, fat, zinc, riboflavin, and palmitic acid. Results for iron were questionable: Lab A, 1.59ยฑ0.14(13); Lab B, 1.65ยฑ0.56 (8); Lab C, 2.68ยฑ0.78(3) mg/100 g . Uncertainty is the standard deviation, with the number of replicate analyses in parentheses. Use two separate t tests to compare results from Lab Cwith those from Lab A and Lab B at the 95 % confidence level. Comment on the sensibility of the t test results and offer your own conclusions.

Internal standard graph -- Data are shown below for chromatographic analysis of naphthalene (C10H8), using deuterated naphthalene (C10D8, in which D is the isotope 2H) as an internal standard. The two compounds emerge from the column at almost identical times and are measured by a mass spectrometer.

(a) Using a spreadsheet such asFigure 4-15, prepare a graph of Equation 5-12 showing peak area ratio(C10H8/C10D8)versus concentration ratio role="math" localid="1663559632352" ([C10H8]/C10D8) . Find the least-squares slope and intercept and their standard uncertainties. What is the theoretical value of the intercept? Is the observed value of the intercept within experimental uncertainty of the theoretical value?

(b) Find the quotientrole="math" localid="1663559638520" [C10H8]/[C10D8]for an unknown whose peak area ratio (C10H8/C10D8) is 0.652. Find the standard uncertainty for the peak area ratio.

(c) Here is why we try not to use 3-point calibration curves. For n = 3 data points, there is n - 2 = 1 degree of freedom, because 2 degrees of freedom are lost in computing the slope and intercept. Find the value of Student's for confidence and 1 degree of freedom. From the standard uncertainty in (b), compute the 95 % confidence interval for the quotient[C10H8]/[C10D8] . What is the percent relative uncertainty in the quotient[C10H8]/[C10D8]? Why do we avoid 3-point calibration curves?

Europium is a lanthanide element found at parts per billion levels in natural waters. It can be measured from the intensity of orange light emitted when a solution is illuminated with ultraviolet radiation. Certain organic compounds that bindEu(III)are required to enhance the emission. The figure shows standard addition experiments in which10.00mLof sample and20.00mLcontaining a large excess of organic additive were placed in 50-mL volumetric flasks. Then Eu(III) standards (0,5.00,10.00,or15.00mL) were added and the flasks were diluted to50.0mLwithH2O. Standards added to tap water contained0.152ng/mL(ppb) of Eu(III), but those added to pond water were 100 times more concentrated (15.2 ng/mL).


(a) Calculate the concentration of Eu(III)(ng/mL) in pond water and tap water.

(b) For tap water, emission peak area increases by.4.61units when 10.00mL of 0.152ng/mL standard are added. This response is4.61 units/1.52ng = 3.03units per ng ofEu(III). For pond water, the response is12.5units when10.00mLof15.2ng/mLstandard are added, or0.0822units per ng. How would you explain these observations? Why was standard addition necessary for this analysis?

Consider a sample that contains analyte at the detection limit defined in Figure. Explain the following statements: There is approximately a 1%chance of falsely concluding that a sample containing no analyte contains analyte above the detection limit. There is a50%chance of concluding that a sample that really contains analyte at the detection limit does not contain analyte above the detection limit.

Distinguish raw data, treated data, and results.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free