Chapter 17: Q39P (page 431)
What are the advantages of using a microelectrode for
voltametric measurements?
Short Answer
The benefits of microelectrodes in voltammetry techniques has been explained.
Chapter 17: Q39P (page 431)
What are the advantages of using a microelectrode for
voltametric measurements?
The benefits of microelectrodes in voltammetry techniques has been explained.
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Get started for freeExplain how the endpoint is detected in a Karl Fischer titration in Figure 17-35.
Fundamentals of Electrolysis
17 - 6.The cell in Figure 17 - 4 is:
Write half-reactions for this cell. Neglecting activity coefficients and the junction potential betweenand KCI(aq), predict the equilibrium (zero-current) voltage expected when the Lugging capillary contacts the electrode. For this purpose, suppose that the reference electrode potential is 0.197Vvs. S.H.E. Why is the observed equilibrium potential+109mV, not the value you calculated?
How would the over potentials change if>1.000Vwere imposed by the
Potentiostat?
17-17. The experiment in Figure 17 - 9 required 5.32mA for 864s for complete reaction of a5.00 - mLaliquot of unknown cyclohexene solution.
(a) How many moles of electrons passed through the cell?
(b) How many moles of cyclohexene reacted?
(c) What was the molarity of cyclohexene in the unknown?
(a) How does the amperometric glucose monitor in Figure 7-12 work? b) Why is a mediator advantageous in the glucose monitor? c) How does the coulometric glucose monitor in Figure 17-14 work? (d) Why does the signal in the amperometric measurement depend on the temperature of the blood sample, whereas the signal in coulometry is independent of temperature? Do you expect the signal to increase or decrease with increasing temperature in amperometry?
(e) Glucoseis present in normal human blood at a concentration near 1g/L How many microcoulombs are required for complete oxidation of glucose in 0.300 of blood in a home glucose monitor if the concentration is 1.00g/L ?
What cathode potential (versus S.H.E.) is required to reduce 99.99%of cd(II) from a solution containing 0.10Mcd (II) in 1,0M ammonia if there is negligible current? Consider the following reactions and assume that nearly all (II) is in the form
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