Chapter 17: Q2P (page 427)
How many hours are required for 0.100 mol of electrons to flow through a circuit if the current is 1.00 A?
Short Answer
Total hours requires for electrons to flow through a circuit is t = 2.68h
Chapter 17: Q2P (page 427)
How many hours are required for 0.100 mol of electrons to flow through a circuit if the current is 1.00 A?
Total hours requires for electrons to flow through a circuit is t = 2.68h
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Get started for free17-16. The sensitivity of a coulometer is governed by the delivery of its minimum current for its minimum time. Suppose thatcan be delivered for 0. 1s.
(a) How many moles of electrons are delivered by 5mAfor 0. 1s ?
(b) How many millilitres of a 0.01 Msolution of a two-electron reducing agent is required to deliver the same number of electrons?
(a) which voltage,orin the diagram is constant in controlled-potential electrolysis? Which are the working, auxiliary, and reference electrodes in the diagram?
(b) Explain how the Luggin capillary in Figure 17-4 measures the electric potential at the opening of the capillary.
For a rotating disk electrode operating at sufficiently great potential, the redox reaction rate is governed by the rate at which analyte diffuses through the diffusion layer to the electrode (Figure 17-15b). The thickness of the diffusion layer is
whereis the diffusion coefficient of reactant is the kinematic viscosity of the liquid
and is the rotation rate (radians/s) of the electrode. There are radians in a circle. The current densityis localid="1655441451764" is
localid="1655441445229"
where nis the number of electrons in the half-reaction, Fis the Faraday constant, and localid="1655441459070" is the concentration of the electroactive species in bulk solution localid="1655441466748" Consider the oxidation oflocalid="1655441474339" in a solution of localid="1655441479067" at +0.90V(versus S.C.E.) at a rotation speed oflocalid="1655441490849" role="math" revolutions per minute. 27The diffusion coefficient oflocalid="1655441497131" and the kinematic viscosity islocalid="1655441503345" Calculate the thickness of the diffusion layer and the current density. If you are careful, the current density should look like the value in Figure 17-16b.
In a coulometric Karl Fischer water analysis, 25.00 mL of pure "dry" methanol required 4.23 C to generate enough I2 to react with residual H2O in the methanol. A suspension of 0.8476 g of finely ground polymeric material in 25.00 mL of the same "dry" methanol required 63.16 C. Find the wt %H2O in the polymer.
Explain how amperometric end-point detection in Figure17-9 operates.
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