Chapter 26: Q4TY (page 738)
What is the effect on injection time if you decrease the applied voltage by a factor of 2?
Short Answer
The electro kinetic injection time is doubled, when the applied voltage is decreased by a factor of 2.
Chapter 26: Q4TY (page 738)
What is the effect on injection time if you decrease the applied voltage by a factor of 2?
The electro kinetic injection time is doubled, when the applied voltage is decreased by a factor of 2.
All the tools & learning materials you need for study success - in one app.
Get started for freeWhat is electroosmosis?
The migration time for in a capillary zone electrophoresis experiment is 17.12 min and the migration time for is 17.78 min. From mobilities in Table 15-1, predict the migration time of Br(The observed value is 19.6 min.)
In ion-exclusion chromatography, ions are separated from nonelectrolytes by an ion-exchange column. Nonelectrolytes penetrate the stationary phase, whereas ions of the same charge as the resin are repelled by the fixed charges. Because co-ions have access to less of the column volume, electrolytes are eluted before nonelectrolytes. The chromatogram shows the separation of trichloroacetic acid (TCA,), dichloroacetic acid (DCA,), and monochloroacetic acid (MCA,) by passage through a cation-exchange resin eluted with 0.01 M HCl. Explain why the three acids are separated and why they emerge in the order shown.
To obtain the best separation of two weak acids in capillary electrophoresis, it makes sense to use the pH at which their charge difference is greatest. Prepare a spreadsheet to examine the charges of malonic and phthalic acid as a function of pH. At what pH is the difference greatest?
(a) A particular solution in a particular capillary has an electroosmotic mobility of and 8.1 . How long will it take a neutral solute to travel 52 cm from the injector to the detector if 27 kV is applied across the 62-cm-long capillary tube at pH 2? At pH 12?(b) An analyte anion has an electrophoretic mobility of How long will it take to reach the detector at pH 2?At pH 12?
What do you think about this solution?
We value your feedback to improve our textbook solutions.