Warning: foreach() argument must be of type array|object, bool given in /var/www/html/web/app/themes/studypress-core-theme/template-parts/header/mobile-offcanvas.php on line 20

What is the effect on injection time if you decrease the applied voltage by a factor of 2?

Short Answer

Expert verified

The electro kinetic injection time is doubled, when the applied voltage is decreased by a factor of 2.

Step by step solution

01

The formulae

The formulae required

Timet=pluglengthspeedKineticinjectiontime(t)=1Appliedelectricfield

02

Finding electrokinetic time

To explain the electrokinetic injection time, when decreasing of applied voltage by a factor of 2. The electro kinetic injection time is

Timet=pluglengthspeed=pluglengthμappEKhKc

In the above equation, the applied electric field is present as a denominator so 2 fractions of applied electric field is doubly increased the electro kinetic injection time.

Kineticinjectiontimet=1Appliedelectricfield

On the other hand, the time is inversely proportional to the applied electric field hence, the decreasing of half of the applied electric field is results the doubly increasing kinetic injection time.

Since the kinetic injection time is inversely proportional to applied electric field, injection time is doubled when applied voltage is halved.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

What is electroosmosis?

The migration time for Cl-in a capillary zone electrophoresis experiment is 17.12 min and the migration time for l-is 17.78 min. From mobilities in Table 15-1, predict the migration time of Br(The observed value is 19.6 min.)

In ion-exclusion chromatography, ions are separated from nonelectrolytes by an ion-exchange column. Nonelectrolytes penetrate the stationary phase, whereas ions of the same charge as the resin are repelled by the fixed charges. Because co-ions have access to less of the column volume, electrolytes are eluted before nonelectrolytes. The chromatogram shows the separation of trichloroacetic acid (TCA,pKa=-0.5), dichloroacetic acid (DCA,), and monochloroacetic acid (MCA,pKa=2.86) by passage through a cation-exchange resin eluted with 0.01 M HCl. Explain why the three acids are separated and why they emerge in the order shown.

To obtain the best separation of two weak acids in capillary electrophoresis, it makes sense to use the pH at which their charge difference is greatest. Prepare a spreadsheet to examine the charges of malonic and phthalic acid as a function of pH. At what pH is the difference greatest?

(a) A particular solution in a particular capillary has an electroosmotic mobility of 1.3×10-8m2/(V×s)atpH2and 8.1 10-8m2/(V×s). How long will it take a neutral solute to travel 52 cm from the injector to the detector if 27 kV is applied across the 62-cm-long capillary tube at pH 2? At pH 12?(b) An analyte anion has an electrophoretic mobility of -1.6×10-8m2/(V×s)How long will it take to reach the detector at pH 2?At pH 12?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free