Chapter 8: Q8P (page 183)
Calculate the activity coefficient of when role="math" localid="1654836623327" by using linear interpolation in Table .
Short Answer
Thus the activity coefficient of when using linear interpolation in Table
Chapter 8: Q8P (page 183)
Calculate the activity coefficient of when role="math" localid="1654836623327" by using linear interpolation in Table .
Thus the activity coefficient of when using linear interpolation in Table
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Get started for freeFind the activity coefficient of each ion at the indicated ionic strength:
(a) Following the example of Mg(OH)2 in Section 8-5, write the equations needed to find the solubility of Ca(OH)2. Include activity coefficients where appropriate. Look up the equilibrium constants in Appendixes F and I.
(b) Suppose that the size of CaOH+= Ca(H2O)5(OH)+ is 500 pm. Including activity coefficients, compute the concentrations of all species, the fraction of hydrolysis (= [CaOH+]/{[Ca2+] + [CaOH+]}), and the solubility of Ca(OH)2 in g/L. The Handbook of Chemistry and Physics lists the solubility of Ca(OH)2 as 1.85 g/L at 00C and 0.77 g/L at 1000C
Why do activity coefficients not appear in the charge andmass balance equations?
Solubility with Activity: Find the concentration of the major species in a saturated aqueous solution of . Consider these reactions:
The equilibrium constant for dissolution of a non ionic compound, such as diethyl ether , in water can be written
At low ionic strength, role="math" localid="1654837696819" for neutral compounds. At high ionic strength, most neutral molecules can be salted out of aqueous solution. That is, when a high concentration typically of a salt such as is added to aqueous solution, neutral molecules usually becomes less soluble. Does the activity coefficient, increases or decreases at high ionic strength?
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