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Calculate the activity coefficient of AI3+when role="math" localid="1654836623327" μ=0.083Mby using linear interpolation in Table 8-1 .

Short Answer

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Thus the activity coefficient of AI3+when μ=0.083M using linear interpolation in Table 8-1is0.202M

Step by step solution

01

Representation of the Table  8-1, which is used for Interpolation.

The given task is to calculate the activity coefficient of AI3+when μ=0.083Musing the linear interpolation in Table 8-1.The table 8-1is given below,

02

Calculating the Activity Coefficient using Interpolation.

In the task,we need to find the activity coefficient using the equation for interpolation.

γ=0.083-0.050.1-0.05×0.18-0.245+0.245=0.202M

Which gives us the activity coefficient of AI3-when μ=0.083M.

Thus the activity coefficient of AI3+ when localid="1654837296480" μ=0.083Mis0.202M

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Most popular questions from this chapter

Find the activity coefficient of each ion at the indicated ionic strength:

(a)SO42-(μ=0.01M)(b)Sc3+(μ=0.005M)(c)Ec3+(μ=0.1M)(d)(CH3CH2)3NH+(μ=0.05M)

(a) Following the example of Mg(OH)2 in Section 8-5, write the equations needed to find the solubility of Ca(OH)2. Include activity coefficients where appropriate. Look up the equilibrium constants in Appendixes F and I.

(b) Suppose that the size of CaOH+= Ca(H2O)5(OH)+ is 500 pm. Including activity coefficients, compute the concentrations of all species, the fraction of hydrolysis (= [CaOH+]/{[Ca2+] + [CaOH+]}), and the solubility of Ca(OH)2 in g/L. The Handbook of Chemistry and Physics lists the solubility of Ca(OH)2 as 1.85 g/L at 00C and 0.77 g/L at 1000C

Why do activity coefficients not appear in the charge andmass balance equations?

Solubility with Activity: Find the concentration of the major species in a saturated aqueous solution of LiF. Consider these reactions:

LiFs֏Li++F-Ksp=Li+γLi+F-γF-LiFs֏LiFaqKionpair=LiFaqγLiFaqF-+H2O֏HF+OH-Kb=KwKaforHFH2O֏KwH++OH-Kw=H+γH+OH-γOH-

  1. Look up the equilibrium constants in the appendixes and write their pK values. The ion pair reaction is the sum of localid="1654945209684" LiFs֏Li++F-from the Appendix FandLi+֏LiFaqfrom Appendix J. write the equilibrium constant expressions and the charge and mass balance.
  2. Create a spreadsheet that uses activities to find the concentration of all species and the ionic strength. Use pH and pOH as independent variables to estimate. It does not work to choose pH and pLi because their concentration fixes that of the other through the relation Ksp=Li+γLi+F-γF-

The equilibrium constant for dissolution of a non ionic compound, such as diethyl ether(CH3CH2OCH2CH3) , in water can be written

ether(I)֏ether(aq)K=[etheraq]γether

At low ionic strength, role="math" localid="1654837696819" γ1 for neutral compounds. At high ionic strength, most neutral molecules can be salted out of aqueous solution. That is, when a high concentration typically (>1M)of a salt such as NaCIis added to aqueous solution, neutral molecules usually becomes less soluble. Does the activity coefficient, γether increases or decreases at high ionic strength?

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