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Why is it not practical to titrate an acid or base that is too weak or too dilute?

Short Answer

Expert verified

It is not feasible to titrate an acid or a base that is too weak because the inflection point, which is so close to the corresponding point, shrinks and becomes more difficult to detect.

Step by step solution

01

Define titration curve.

  • The plot of the pH of the analyte solution versus the volume of the titrant added as the titration advances is known as a titration curve.

  • Titration curves demonstrate how the pH of a solution varies when a known chemical is added to it, therefore each point along the curve offers you information on the pH of the solution as the volume of the known chemical grows.

02

Reason for not titrating an acid or a base that is too dilute.

  • Inflection point and equivalence points are the two points that are easy to identify in a titration curve.

  • Weak acids are rarely titrated against weak bases because the color shift caused by the indicator is generally rapid, making it difficult for the viewer to perceive the change.

  • The titration can be completed with just one drop, which is far too tiny to rely on.

  • As the concentration and/or intensity of the acid/base drop, it becomes more difficult to detect the end of the titration.

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Most popular questions from this chapter

Cresol red has two transition ranges listed in Table 11-3. What color would you expect it to be at the following pH values?

(a)0(b)1(c)6(d)9

A solution was prepared from 1.023 g of the primary standard tris (Table 11-4) plus 99.367 g of water; 4.963 g of the solution were titrated with 5.262 g of aqueousHNO3to reach the methyl red endpoint. Calculate the concentration of the HNO3(expressed as mol HNO3/kg solution)

In-1Spectrophotometry with indicators.* Acid-base indicators arc themselves acids or bases. Consider an indicator. HIn. which dissociates according to the equation

HInโ‡ŒKaH++In-

The molar absorptivity,. is role="math" localid="1654932356442" 2080M-1cm-1for HIn and 14200M-1cm-1for In-1. at a wavelength of 440 nm.

(a) Write an expression for the absorbance of a solution containing HIn at a concentration [HIn] and role="math" localid="1654932619574" In-1at a concentration role="math" localid="1654932655635" In-in a cell of pathlength 1.00 cm. The total absorbance is the sum of absorbances of each component.

(b) A solution containing indicator at a formal concentration of role="math" localid="1654931801074" 1.84ร—104-Mis adjusted to pH 6.23and found to exhibit an absorbance of 0.868 at 440 nm. Calculate pKa for this indicator.

11-19. Sketch the general appearance of the curve for the titration of a weak diprotic acid withNaOH. What chemistry governs the pHin each distinct region of the curve?

Titrating diprotic acid with strong base.

Prepare a family of graphs for the titration of 50.0 mL of 0.020 0 M H2A with 0.100 M NaOH. Consider the following cases: (a) pK1 = 4.00, pK2 =8.00; (b) pK1 = 4.00, pK2 = 6.00; (c) pK1 = 4.00, pK2 = 5.00

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