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Finding the End Point with a pH Electrode

11-33What is a Gran plot used for?

Short Answer

Expert verified

The gran plot used to locate the end point of the titration by using the data right before the equivalence point

Step by step solution

01

Titration of Diprotic Systems

  • Titration of a diprotic acid with a specified quantity of NaOH solution
  • Diprotic acid's molecular weight (or molar mass) is expressed in grams per mole.
  • You can determine the original acid sample's mass in grams by weighing it.
  • The volume of NaOH titrant required to achieve the first equivalence point can be used to calculate moles.
02

Determine the gran plot used for

Gran plot is used to locate the end point of the titration by using the data right before the equivalence point, for example from 0.8Veor 0.9Veup to Ve.

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Most popular questions from this chapter

Titration on Diprotic Systems

11-30. This problem deals with the amino acid cysteine, which we will abbreviate H2C.

(a) A 0.0300Msolution was prepared by dissolving dipotassium cysteine, in water. Then of this solution were titrated with 0.0600MHCIO4. Calculate the pHat the first equivalence point.

(b) Calculate the quotient [C2-]/[HC-] in a solution of cysteinium bromide (the saltH3C+Br-).

The Kjeldahl procedure was used to analyze 256 mL of a

solution containing 37.9 mg protein/mL The liberated NH3 was

collected in 5.00 mL of 0.033 6 M HCl, and the remaining acid

required 6.34 mL of 0.010 M NaOH for complete titration. What is

the weight percent of nitrogen in the protein?

(a) Uncertainty in formula mass. In an extremely-high precision gravimetric titration, the uncertainty in the formula mass of the primary standard could contribute to the uncertainty of the result. Read about uncertainty in molecular mass in Appendix B. Express the formula mass of potassium hydrogen phthalate, C8H5O4Kwith its 95% confidence interval based on a rectangular distribution of uncertainty of atomic mass with a coverage factor of k 5 2.

(b) Systematic uncertainty in reagent purity. The manufacturer of potassium hydrogen phthalate states that the purity is 1.000 00 60.000 05. In the absence of further information, we assume that the distribution of uncertainty is rectangular. What standard uncertainty would you use for the purity of this reagent

Find the equilibrium constant for the reaction of MES (Table9-2) withNaOH .

Why is it more accurate to use a primary standard with a

high equivalent mass (the mass required to provide or consume 1

mol of H1) than one with a low equivalent mass?

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