Chapter 11: Q33P (page 260)
Finding the End Point with a pH Electrode
What is a Gran plot used for?
Short Answer
The gran plot used to locate the end point of the titration by using the data right before the equivalence point
Chapter 11: Q33P (page 260)
Finding the End Point with a pH Electrode
What is a Gran plot used for?
The gran plot used to locate the end point of the titration by using the data right before the equivalence point
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. This problem deals with the amino acid cysteine, which we will abbreviate .
(a) A 0.0300Msolution was prepared by dissolving dipotassium cysteine, in water. Then of this solution were titrated with . Calculate the pHat the first equivalence point.
(b) Calculate the quotient in a solution of cysteinium bromide (the salt).
The Kjeldahl procedure was used to analyze 256 mL of a
solution containing 37.9 mg protein/mL The liberated NH3 was
collected in 5.00 mL of 0.033 6 M HCl, and the remaining acid
required 6.34 mL of 0.010 M NaOH for complete titration. What is
the weight percent of nitrogen in the protein?
(a) Uncertainty in formula mass. In an extremely-high precision gravimetric titration, the uncertainty in the formula mass of the primary standard could contribute to the uncertainty of the result. Read about uncertainty in molecular mass in Appendix B. Express the formula mass of potassium hydrogen phthalate, with its 95% confidence interval based on a rectangular distribution of uncertainty of atomic mass with a coverage factor of k 5 2.
(b) Systematic uncertainty in reagent purity. The manufacturer of potassium hydrogen phthalate states that the purity is 1.000 00 60.000 05. In the absence of further information, we assume that the distribution of uncertainty is rectangular. What standard uncertainty would you use for the purity of this reagent
Find the equilibrium constant for the reaction of MES (Table with .
Why is it more accurate to use a primary standard with a
high equivalent mass (the mass required to provide or consume 1
mol of H1) than one with a low equivalent mass?
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