Question

A reversible reaction is one which : (a) Proceeds in one direction (b) Proceeds in both directions (c) Proceeds spontaneously (d) All the statements are wrong

Short answer

Option (b) is correct as a reversible reaction proceeds in both directions.

Step-by-step solution

Understanding the Concept of a Reversible Reaction

A reversible reaction is one where the reactants form products, which can themselves react together to form the reactants again. This means that this type of reaction can proceed in both forward and reverse directions under certain conditions.

Analyzing the Given Options

Option (a) suggests that the reaction proceeds in one direction, which is characteristic of an irreversible reaction, not a reversible one. Option (c) refers to spontaneity, which is a different concept that does not solely determine if a reaction is reversible. Option (d) suggests that all statements are wrong, which is not true since we know some reactions are indeed reversible.

Identifying the Correct Answer

Option (b) states that a reversible reaction proceeds in both directions, which aligns with the definition of a reversible reaction. Therefore, option (b) is the correct choice.

Key concepts

Chemical Equilibrium

Chemical equilibrium represents a state in a chemical reaction where the rate of the forward reaction equals the rate of the reverse reaction, meaning that the concentrations of reactants and products remain constant over time, though not necessarily equal. It is important to understand that the equilibrium is dynamic. This indicates that while the overall concentrations don't change, the molecules are still reacting with one another. Equilibrium can be reached in both reversible reactions, where compounds can react in both forward and reverse directions, and is indicated by the equilibrium constant (\( K_{eq} \)), which quantifies the ratio of product concentrations to reactant concentrations at equilibrium.

For learners grappling with this topic, it’s helpful to visualize a balance scale that is evenly positioned; this represents the equilibrium state. Neither side is heavier (faster) than the other; reaction rates are perfectly balanced. This analogy can simplify the understanding of equilibrium without getting lost in the complexity of chemical reactions.

Irreversible Reaction

An irreversible reaction, in contrast to a reversible one, proceeds in one direction only, leading to a complete consumption of the reactants. Once the reactants have been converted to products, the reaction cannot naturally go backwards to re-form the original reactants. This is similar to pressing a 'one-way road' button from reactants to products; there's no turning back.

Most chemical reactions in real-life scenarios are considered irreversible due to the reactants undergoing permanent change. Examples include combustion, precipitation, and the mixing of an acid with a base to neutralize each other. In educational settings, picturing an irreversible reaction as a slide from which you cannot climb back up could enhance a student's understanding of this concept.

Reaction Spontaneity

Reaction spontaneity refers to whether a chemical reaction can occur without the continuous input of energy from an external source. Spontaneous reactions, despite the name, do not necessarily happen quickly; they may proceed at any speed, but the essential point is that they are thermodynamically favorable under the conditions provided. The spontaneity of a reaction is determined by factors including enthalpy, entropy, and temperature, and is often assessed through the Gibbs free energy formula: \( G = H - TS \), where \( G \) is the Gibbs free energy, \( H \) the enthalpy, \( T \) the temperature, and \( S \) the entropy.

A negative Gibbs free energy implies that the reaction is spontaneous. To further support learners, the concept of spontaneity might be equated to a ball rolling downhill—once started (after reaching the activation energy), the ball continues rolling without additional pushing, which in this metaphor, represents the spontaneous progression of the reaction.