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In their Memoir on Heat,published in 1783, Lavoisier and Laplace reported, “The heat necessary to melt ice is equal to three quarters of the heat that can raise the same mass of water from the temperature of the melting ice to that of boiling water” (English translation). Use this 18th-century observation to compute the amount of heat (in joules) needed to melt 1.00 g ice. Assume that heating 1.00 g

water requires 4.18 J of heat for each1.000C throughout the range from00C to 1000C.

Short Answer

Expert verified

The heat required to melt 1.00 g of ice is 314 J.

Step by step solution

01

The given Information;

Here, two bodies of equal mass and different temperatures are kept in thermal contact. Their specific heat capacities are inversely proportional to the change in temperature undergoing on reaching their final temperature.

02

The heat

Heat constitutes an important term in thermodynamics denoted as q. There are numerous methods of heat transfer, and they are conduction and convention.

03

The amount of heat needed to melt 1.00 g of ice.

The amount of heatneeded to raise the 1.00 g of water from the meltingice temperature00C to that of boiling water is;

q = Mcs∆T= 1.00 g×4.18 Jg0C×1000C - 00C= 418 J

This heat is equal to three-quarters of the heat that can raise the same mass of water by 1000C.

Therefore, theamount of heat neededto melt 1.00 g of ice is:

34q =34418 J= 314 J

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Most popular questions from this chapter

Nitro methane, \({\rm{C}}{{\rm{H}}_3}{\rm{N}}{{\rm{O}}_2}\), is a good fuel. It is a liquid at ordinary temperatures. When the liquid is burned, the reaction involved is chiefly

\(2{\rm{C}}{{\rm{H}}_3}{\rm{N}}{{\rm{O}}_2}(\ell ) + \frac{3}{2}{{\rm{O}}_2}(g) \to \mathop 2\limits_2 {\rm{C}}{{\rm{O}}_2}(g) + {{\rm{N}}_2}(g) + 3{{\rm{H}}_2}{\rm{O}}(g)\). The standard enthalpy of formation of liquid nitro methane at 250C is \( - 112\;{\rm{kJ}}\;{\rm{mo}}{{\rm{l}}^{ - 1}}\), other relevant values can be found in Appendix D.

(a) Calculate the enthalpy change in the burning of \(1\;{\rm{mol}}\) liquid nitro methane to form gaseous products at 250C. State explicitly whether the reaction is endothermic or exothermic.

(b) Would more or less heat be evolved if gaseous nitro methane were burned under the same conditions? Indicate what additional information (if any) you would need to calculate the exact amount of heat, and show just how you would use this information.

Consider the free, isothermal (constant T) expansion of an ideal gas. “Free” means that the external force is zero, perhaps because a stopcock has been opened and the gas is allowed to expand into a vacuum. Calculate ΔUfor thisirreversible process. Show that q = 0, so that the expansion is also adiabatic(q=0) for an ideal gas. This is analogous to a classic experiment first performed by Joule.

For each of the following reactions, the enthalpy change given is that measured when the numbers of moles of reactants and products taking part in the reaction are as given by their coefficients in the equation. Calculate the enthalpy change whengram of the underlined substance is consumed or produced.

  1. Ca(s)+Br2()¯CaBr2(s)ΔH=-683kJ
  2. 6Fe2O3(s)4Fe3O4¯(s)+O2(g)ΔH=472KJ
  3. 2NaHSO4¯(s)2NaOH(s)+2SO2(g)+O2(g),ΔH=+806kJ

Ammonium nitrate dissolves in water according to the reaction

NH4NO3(s)NH4+(aq)+NO3-(aq).

(a) Calculate the standard enthalpy change ΔHfor this reaction, using data from Appendix D.

(b) Suppose 15.0gNHNH3 is dissolved in 0.100Lwater at 20.00C. Calculate the temperature reached by the solution, assuming it to be an ideal solution with a heat capacity close to that 100g ofpure water(418JK-1).

(c) From a comparison with the results of problem 43 and 44, suggest a practical application of this dissolution reaction?

Some nitrogen for use in synthesizing ammonia is heated slowly, maintaining the external pressure close to the internal pressure of 50.0 atm, until its volume has increased from 542 to 974 L. Calculate the work done on the nitrogenas it is heated, and express it in joules.

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