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A sample of pure solid naphthalene (C10H8) weighing 0.6410 g is burned completely with oxygen to (CO2) and (H2O) in a constant-volume calorimeter at 25°C. The amount of heat evolved is observed to be 25.79 kJ.

(a) Write and balance the chemical equation for the combustion reaction.

Short Answer

Expert verified

Subpart (a)

C10H8+12O210CO2+4H2O

Step by step solution

01

Given Information;

The weight of naphthalene is 0.6410 g.

The amount of heat evolved is 25.79 kJ.

02

Combustion reaction;

The fuel gets subjected to oxidation by combining with an oxidizing agent. This leads to energy liberation in the form of heat. This reaction is termed a combustion reaction.

03

The balanced chemical equation for the combustion reaction.Subpart (a)

Let us consider the reaction;

C10H8+O2CO2+H2O

Here, the carbon atoms are not balanced. This can be balanced by placing a coefficient of 10 before CO2on the right.

C10H8+O210CO2+H2O

The hydrogen atoms are not balanced. This can be balanced by placing a coefficient of 4 before H2O on the right. The resulting equation is:

C10H8+O210CO2+4H2O

The oxygen atoms can be balanced by placing a coefficient of 12 before O2as:

C10H8+12O210CO2+4H2O

Therefore, the balanced chemical equation for the combustion reaction is:

C10H8+12O210CO2+4H2O

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Most popular questions from this chapter

Suppose2.00mol of an ideal gas is contained in a heat insulated cylinder with a moveable frictionless piston. Initially, the gas is at1.00atm and0°c . The gas is compressed reversibly to 2.00 atm. The molar heat capacity at constant pressure, cp, equals29.3JK-1mol-1 . Calculate the final temperature of the gas, the change in its internal energyΔU, , and the work done on the gas.

(a) Draw Lewis diagrams forO2,CO2,H2O,CH4,C8H18andC2H5OH. InC8H18, the eight carbon atoms form a chain with single bonds; inC2H5OH, the two carbon atoms are bonded to one another. Using average bond enthalpies from Table 12.5, compute the enthalpy change in each of the following reactions, if 1 mol of each carbon compound is burned, and all reactants and products are in the gas phase.

(b)CH4+2O2CO2+2H2O(burning methane, or natural gas)

(c)C8H18+252O28CO2+9H2O(burning octane, in gasoline)

(d)C2H5OH+3O22CO2+3H2O(burning ethanol, in gasohol)

The specific heat capacities of the metals nickel, zinc, rhodium, tungsten, gold, and uranium at 25°C are 0.444, 0.388, 0.243, 0.132, 0.129, and 0.116JK-1g-1, respectively. Calculate the molar heat capacities of these six metals. Note how closely the molar heat capacities for these metals, which were selected at random, cluster about a value of 25JK-1mol-1. The rule of Dulong and Petitstates that the molar heat capacities of the metallic elements are approximately 25JK-1mol-1.

(a) Calculate the change in enthalpy when 2.00 moles of argon is heated from298K to573K at constant pressure of 1 atmosphere.

(b) Calculate the change in enthalpy when moles of ethylene is taken through the same process. In both cases assume the heat capacity values predicted by equipartition are valid through the temperature range stated.

Question 89: By considering the nature of the intermolecular forces in each case, rank the following substances from smallest to largest enthalpy of vaporization: KBr,Ar,NH3 , and He.Explain your reasoning.

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