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Suppose 61.0 g hot metal, which is initially at 1200C, is plunged into 100.0 g water that is initially at . The metal cools down and the water heats up until they reach a common temperature of 26.390C. Calculate the specific heat capacity of the metal, using4.18JK-1g-1 as the specific heat capacity of the water.

Short Answer

Expert verified

The specific heat capacity of the metal is .0.468

Step by step solution

01

Specific heat capacity

Specific heat capacity exhibits variation with temperature.Each state of matter possesses a unique value of specific heat capacity.

02

Calculating the specific heat capacity of the metal

The mass of the hot metal is 61.0 g.

The mass of water is 100.0 g.

The initial temperature of water is 20.000C.

The initial temperature of the metal is 120.000C.

The final temperature of the metal is 26.390C

The specific heat capacity of the metal can be found as:

∆Qsys=∆Qmetal+∆Qwater= 0Qmetal+∆Qwater=mmetalCs,metal∆Tmetal+mwaterCs,water∆Twater= 0Cs,metal=mwaterCs,water∆Twatermmeta∆lTmetal

Where, mmetaland mwaterdenote the mass of metal and water respectively.

Cs,waterand Cs,metaldenote the specific heat capacity of water and metal respectively.

∆Twaterand ∆Tmetaldenote the temperature of the water and metal.

On further solving,

Cs,metal=mwaterCs,water×Twatermmetal×Tmetal=100 g×4.18 JK- 1g- 1×6.39 K61.0 g-×93.61 K=2671.02JK- 1g- 15710.21= 0.468JK- 1g- 1

Hence, the specific heat capacity of the metal is 0.468 JK- 1g- 1

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Most popular questions from this chapter

The following table shows how the specific heat at constant pressure of liquid helium changes with temperature. Note the sharp increase over this temperature range:

Temperature (K):

1.80 1.85 1.90 1.95 2.00 2.05 2.10 2.15

csJK-1g-1:

2.81 3.26 3.79 4.42 5.18 6.16 7.51 9.35

Estimate how much heat it takes at constant pressure to increase the temperature of 1.00 g He(l) from 1.8 to 2.15 K. (Hint:For each temperature interval of 0.05 K,

take the average, cs, as the sum of the values at the ends of the interval divided by 2.)

The gas most commonly used in welding is acetylene, \({{\rm{C}}_2}{{\rm{H}}_2}(g)\). When acetylene is burned in oxygen, the reaction is

\({{\rm{C}}_2}{{\rm{H}}_2}(g) + \frac{s}{2}{{\rm{O}}_2}(g) \to 2{\rm{C}}{{\rm{O}}_2}(g) + {{\rm{H}}_2}{\rm{O}}(g)\)

(a) Using data from Appendix D, calculate \(\Delta {H^*}\) for this reaction.

(b) Calculate the total heat capacity of\(2.00\;{\rm{mol}}\),\({\rm{C}}{{\rm{O}}_2}(g)\) and \(1.0D\)mol \({{\rm{H}}_2}{\rm{O}}(g)\), using \({C_p}\left( {{\rm{C}}{{\rm{O}}_2}(g)} \right) = 37{\rm{J}}{{\rm{K}}^{ - 1}}\;{\rm{mo}}{{\rm{l}}^{ - 1}}\) and \({C_{\rm{p}}}\left( {{{\rm{H}}_2}{\rm{O}}(g)} \right) = 36\;{\rm{J}}\;{{\rm{K}}^{ - 1}}\;{\rm{mo}}{{\rm{l}}^{ - 1}}\).

(c) When this reaction is performed in an open flame, almost all the heat produced in part (a) goes to increase the temperature of the products. Calculate the maximum flame temperature that is attainable in an open flame burning acetylene in oxygen. The actual flame temperature would be lower than this because heat is lost to the surroundings.

During his honeymoon in Switzerland, James Joule is said to have used a thermometer to measure the temperature difference between the water at the top and at the bottom of a waterfall. Take the height of the waterfall to be hand the acceleration of gravity, g,to be 9.81ms-2. Assuming that all the potential energy changemgh of a mass mof water is used to heat that water by the time it reaches the bottom, calculate the temperature difference between the top and the bottom of a waterfall 100 meters high. Take the specific heat capacity of water

to be 4.18JK-1g-1

When a ball of mass mis dropped through a height difference ,its potential energy changes by the amount mgh,where gis the acceleration of gravity, equal to 9.81ms-2. Suppose that when the ball hits the ground, all that energy is converted to heat, increasing the temperature of the ball. If the specific heat capacity of the material in the ball is 0.850JK-1g-1, calculate the height from which the ball must be dropped to increase the temperature of the ball by 1.000C.

The specific heat capacities of the metals nickel, zinc, rhodium, tungsten, gold, and uranium at 25°C are 0.444, 0.388, 0.243, 0.132, 0.129, and 0.116JK-1g-1, respectively. Calculate the molar heat capacities of these six metals. Note how closely the molar heat capacities for these metals, which were selected at random, cluster about a value of 25JK-1mol-1. The rule of Dulong and Petitstates that the molar heat capacities of the metallic elements are approximately 25JK-1mol-1.

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