Chapter 21: P 35 (page 934)
Question: Will the presence of Frenkel defects change the measured density of a crystal?
Short Answer
There is no change in the measured density of a crystal because each vacancy is accompanied by an interstitial.
Chapter 21: P 35 (page 934)
Question: Will the presence of Frenkel defects change the measured density of a crystal?
There is no change in the measured density of a crystal because each vacancy is accompanied by an interstitial.
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Get started for freeQuestion: Sodium has the body-centered cubic structure, and its lattice parameter is .
(a) How many Na atoms does a unit cell contain?
(b) What fraction of the volume of the unit cell is occupied by Na atoms, if they are represented by spheres in contact with one another?
Question: Repeat the determinations of the preceding problem for the NaCl crystal, referring to Figure 21.16.
Identify the symmetry elements of themolecule (see Fig. 3.20a).
(a) Use the BornโHaber cycle, with data from Appendices D and F, to calculate the lattice energy of LiF.
(b) Compare the result of part (a) with the Coulomb energy calculated by using an Li-F separation of in the LiF crystal, which has the rock-salt structure.
Nickel has an fcc structure with a density of .
(a) Calculate the nearest neighbor distance in crystalline nickel.
(b) What is the atomic radius of nickel?
(c) What is the radius of the largest atom that could fit into the interstices of a nickel lattice, approximating the atoms as spheres?
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