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Question: Compare oxide ceramics such as aluminaAl2O3and magnesia (MgO), which have significant ionic character, with covalently bonded nonoxide ceramics such as silicon carbide (SiC) and boron carbide; (B4Csee Problems 19 and 20) with respect to thermodynamic stability at ordinary conditions.

Short Answer

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Aluminium oxide is an electric insulator and has a relatively high thermal conductivity for a ceramic metal whereas pure MgO isn't conductive and have a high resistance to current at temperature.

Step by step solution

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Step 1:

The most common form of Aluminium oxide is Corundum, which is insoluble in water. It is responsible for the resistance of metallic aluminium. Aluminium oxide is an electric insulator and has a relatively high thermal conductivity for a ceramic metal.

Aluminium oxide is answerable for the resistance of metallic aluminium to weathering. Metallic aluminium is incrediblyreactive with atmospheric oxygen, and a skinny passivation layer of aluminum oxide alumina is an amphoteric substance, meaning it can react with both acids and bases, like acid and caustic soda, acting as an acid with a base and a base with an acid, neutralising the opposite and producing a salt.

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Step 2:

Pure MgO isn't conductive and have a high resistance to current at temperature. MgO is prized as a refractory material, i.e. a solid that's physically and chemically stable at high temperatures. it's two useful attributes: high thermal conductivity and low electrical conductivity. Filling the spiral Calrod range top heating elements on kitchen electric stoves are the major use.

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Most popular questions from this chapter

A cylindrical sample of solid germanium has length 55.0 mm and diameter 5.0 mm. In a test circuit, 0.150 A of current flowed through this sample when the voltage applied between its ends was 17.5 V. What is the electrical conductivity of this sample?

In a light-emitting diode (LED), which is used in displays on electronic equipment, watches, and clocks, a voltage is imposed across an n–p semiconductor junction. The electrons on the n side combine with the holes on the p side and emit light at the frequency of the band gap. This process can also be described as the emission of light as electrons fall from levels in the conduction band to empty levels in the valence band. It is the reverse of the production of electric current by illumination of a semiconductor. Many LEDs are made from semiconductors that have the general composition GaAs1-xPx.When x is varied between 0 and 1, the band gap changes and, with it, the color of light emitted by the diode. When X=0.4, the band gap is 2.9×10-19J. Determine the wavelength and color of the light emitted by this LED.

Question: A sample of silicon doped with antimony is an n-type semiconductor. Suppose a small amount of gallium is added to such a semiconductor. Describe how the conduction properties of the solid will vary with the amount of gallium added.

Question: The standard free energy of formation of boron carbide (B4C ) is 71kJ.mol-1. Determine the standard free energy change when 1.00 mol reacts with oxygen to form B2O3sandCO2(g) . Is boron carbide thermodynamically stable in the air at room conditions?

Draw a Lewis electron-dot diagram for the cyclosilicate ion Si6O1812- which forms part of the structures of beryl and emerald.

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