Chapter 2: Q47AP (page 52)
Aluminum carbide reacts with water to produce gaseous methane . Calculate the mass of methane formed from 63.2g
Short Answer
Mass of methane produce in the reaction is 21.1g
Chapter 2: Q47AP (page 52)
Aluminum carbide reacts with water to produce gaseous methane . Calculate the mass of methane formed from 63.2g
Mass of methane produce in the reaction is 21.1g
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with all reactants and products gaseous (for simplicity) and an equilibrium constant K.
(a) Assume that the elementary steps in the reaction are those indicated by the stoichiometric equation (in each direction), with specific rate constants for the forward reaction and the reverse reaction, respectively, kf and kr. Derive the relation between kf, kr, and K. Comment on the general validity of the assumptions made about the relation of elementary steps and the stoichiometric equation and also on the general validity of K.
(b) Assume that the reaction as written is exothermic. Explain what this implies about the change of K with temperature. Explain also what it implies about the relation of the activation energies of the forward and reverse reactions and how this relation is consistent with your statement about the variation of K with temperature.
A patient has a "cholesterol count" of 214. Like many blood-chemistry measurements, this result is measured in units of milligrams per deciliter
(a) Determine the molar concentration of cholesterol in this patient's blood, taking the molar mass of cholesterol to be .
(b) Estimate the molality of cholesterol in the patient's blood.
(c) If 214 is a typical cholesterol reading among men in the United States, determine the volume of such blood required to furnish 8.10kg of cholesterol.
69.The water in a pressure cooker boils at a temperature greater than 100°C because it is under pressure. At this higher temperature, the chemical reactions associated with the cooking of food take place at a greater rate.
(a) Some food cooks fully in 5 min in a pressure cooker at 112°C and in 10 minutes in an open pot at 100°C. Calculate the average activation energy for the reactions associated with the cooking of this food.
(b) How long will the same food take to cook in an open pot of boiling water in Denver, where the average atmospheric pressure is 0.818 atm and the boiling point of water is 94.4°C?
Question: Many important fertilizers are ionic compounds that contain the elements nitrogen, phosphorus, and potassium because these are frequently the limiting plant growth nutrients in soil.
(a)Write the chemical formulas for the following chemical fertilizers: ammonium phosphate, potassium nitrate, ammonium sulfate.
(b)Calculate the mass percentage of nitrogen, phosphorus, and potassium for each of the compounds in part (a).
Acetylene reacts with hydrogen in the presence of a catalyst to form ethane according to the following reaction:
The pressure of a mixture of acetylene and an excess of hydrogen decreases from to in a vessel of a given volume after the catalyst is introduced, and the temperature is restored to its initial value after the reactionreaches completion. What was the mole fraction of acetylene in the original mixture?
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