Chapter 2: Q12.6-31P (page 36)
Calculate the enthalpy change when 2.38gcarbon monoxidevaporizes at its normal boiling point. Use data from Table 12.2.
Short Answer
The enthalpy change, H=512.8J.
Chapter 2: Q12.6-31P (page 36)
Calculate the enthalpy change when 2.38gcarbon monoxidevaporizes at its normal boiling point. Use data from Table 12.2.
The enthalpy change, H=512.8J.
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62.In Section 18.4 we considered the following mechanism for the reaction of Br2with H2
Although this is adequate for calculating the initial rate of reaction, before product HBr builds up, there is an additional process that can participate as the reaction continues
(a) Write an expression for the rate of change of [H].
(b) Write an expression for the rate of change of [Br].
(c) As hydrogen and bromine atoms are both short-lived species, we can make the steady-state approximation and set the rates from parts (a) and (b) to 0. Express the steady-state concentrations [H] and [Br] in terms of concentrations of H2, Br2, HBr, and M. [Hint: Try adding the rate for part (a) to that for part (b).]
(d) Express the rate of production of HBr in terms of concentrations of H2, Br2, HBr, and M.
Aluminum carbide reacts with water to produce gaseous methane . Calculate the mass of methane formed from 63.2g
Quantum mechanics predicts that the energy of the ground state of the atom is . Insight into the magnitude of this quantity is gained by considering several methods by which it can be measured.
(a) Calculate the longest wavelength of light that will ionizeatoms in their ground state.
(b) Assume the atom is ionized by collision with an electron that transfers all its kinetic energy to the atom in the ionization process. Calculate the speed of the electron before the collision. Express your answer in meters per second and miles per hour (miles).
(c) Calculate the temperature required to ionize a atom in its ground state by thermal excitation. (Hint: Recall the criterion for thermal excitation of an oscillator in Planck's theory of blackbody radiation is that.)
Question: The gaseous compounds allene and propyne are isomers with formula C3H4. Calculate the equilibrium constant and the standard enthalpy change at 25°C for the isomerization reaction Allene(g)Propyne(g)from the following data, all of which apply to 298 K:
| ||
Allene | 192 | 202 |
Propyne | 185 | 194 |
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