Chapter 7: Q2P (page 324)
Is it possible for motor fuel to have a negative octane rating? Explain.
Short Answer
If a fuel has a negative octane rating then such fuel causes more "knocking" than -heptane which is worst at the time.
Chapter 7: Q2P (page 324)
Is it possible for motor fuel to have a negative octane rating? Explain.
If a fuel has a negative octane rating then such fuel causes more "knocking" than -heptane which is worst at the time.
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Get started for freeHydrogen can be added to a certain unsaturated hydrocarbon in the presence of a platinum catalyst to form hexane. When the same hydrocarbon is oxidized with , it yields acetic acid and butanoic acid. Identify the hydrocarbon and write balanced chemical equations for the reactions.
The naphthalene molecule has a structure that corresponds to two benzene molecules fused together:
The electrons in this molecule are delocalized over the entire molecule. The wavelength of maximum absorption in benzene is 255 nm. Will the corresponding wavelength in naphthalene be shorter or longer than 255 nm?
Consider the following proposed structures for benzene, each of which is consistent with the molecular formula C6H6.
(i)
(ii)
(iii)
(iv)
(v)
(a)When benzene reacts with chlorine to give C6H5Cl, only one isomer of that compound forms. Which of the five proposed structures for benzene is consistent with this observation?
A compound C4H11N is known from its reactivity and spectroscopic properties to have no hydrogen atoms attached directly to the nitrogen atom. Write all structural formulas consistent with this information.
(a) The herbicide 2,4-D (see Fig. 7.33a) is an ether. Write the structural formulas of the two alcohol or phenol compounds that, on condensation, would form this ether. (The usual method of synthesis does not follow this plan.)
(b) Suppose that hydrogen atoms replace the chlorine atoms and a -CH3 group replaces the carboxylic acid group in the two compounds in part (a). Name the resulting compounds.
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