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The working curve for the determination of dopamine at a nanoneedle electrode by differential-pulse voltammetry (Figure 25-38) was constructed from the following table of data.

ConcentrationDopamine,mMPeak Current,nA0.0930.660.1941.310.4002.640.5964.510.9915.97

(a) Use Excel to perform a least-squares analysis of the data to determine the slope, intercept, and regression statistics, including the standard deviation about regression.

(b) Use your results to find the concentration of dopamine in a sample solution that produced a peak current of 2.92 nA. This value is the average of duplicate experiments.

(c) Calculate the standard deviation of the unknown concentration and its 95%confidence interval assuming that each of the data in the table was obtained in a single experiment.

Short Answer

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Most popular questions from this chapter

Sulfate ion can be determined by an amperometric titration procedure using Pb2+as the titrant. If the potential of a rotating mercury film electrode is adjusted to 21.00 V versus SCE, the current can be used to monitor the Pb2+concentration during the titration. In a calibration experiment, the limiting current, after correction for background and residual currents, was found to be related to the Pb2+concentration by i1=10cPb2+, where i1is the limiting current in mA and cPb2+is the Pb2+concentration in mM.

The titration reaction is

role="math" localid="1653990390811" SO42-+Pb2+โ‡ŒPbSO4sKsp=1.6ร—10-8

If 25.00mLof0.020MNa2SO4is titrated with 0.030MPb(NO3)2, develop the titration curve in spreadsheet format and plot the limiting current versus the volume of titrant.

Suggest how Equation 25-13could be used to determine the half-wave potential of a species reacting at an electrode.

What is the purpose of the electrodeposition step in stripping analysis?

In experiment 1, a cyclic voltammogram at an HMDE was obtained from a 0.159-mM solution of data-custom-editor="chemistry" Pb2+ at a scan rate of 2.9V/s. In experiment 2, a second CV is to be obtained from a 4.26-mM solution of data-custom-editor="chemistry" Cd2+ using the same HMDE. What must the scan rate be in experiment 2 to record the same peak current in both experiments if the diffusion coefficients of data-custom-editor="chemistry" Cd2+andPb2+ are 0.72ร—10-5cm2s-1and0.98cm2s-1, respectively. Assume that the reductions of both cations are reversible at the HMDE.

Why is the reference electrode placed near the working electrode in a three-electrode cell?

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