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What are the advantages of microfabricated ISEs? Describe typical applications of this type of sensor.

Short Answer

Expert verified

A little amount of analyte is required for microfabricated ISEs. They are typically used in the investigation of the cell's morphology.

Step by step solution

01

Concept introduction

Membrane Indicator Electrodes or Ion Selective Electrodes (ISEs) are used to monitor the pHof a solution and are made up of a thin glass membrane. Only the intended ions can pass across the membrane. The transportation of ions from a higher concentration to a lower concentration via the membrane creates a potential difference near the membrane.

02

Advantages

  • They are very small in size.
  • A very small amount of solution is needed for them to operate.
  • They have selective reactivity with the analyte.
03

Applications

  • Drug analysis
  • Study of cellular level
  • Biosensors
  • Environment monitoring

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Most popular questions from this chapter

The standard electrode potential for the reduction of the Cu(II) complex of EDTA is given by

CuY2-+2e-โ‡ŒCu2+s+Y4-Eo=0.13V

Calculate the formation constant for the reaction

Cu2++Y4-โ‡ŒCuY2-

What is meant by Nernstian behavior of an indicator electrode?

(a) Calculate the standard potential for the reaction

Ag3AsO4(s)+3e-โ‡Œ3Ag(s)+AsO43-

ForAg3AsO4,Ksp=1.2ร—10-22.

(b) Give a schematic representation of a cell with a silver indicator electrode and an SCE as reference that could be used for determining localid="1648042702202" AsO43-.

(c) Derive an equation that relates the measured potential of the cell in (b) to pAsO4(assume that the junction potential is zero).

(d) Calculate the pAsO4of a solution that is saturated with Ag3AsO4and contained in the cell described in (b) if the resulting potential is 0.193 V.

The formation constant for the mercury(II) acetate complex is

Hg2++2OAc-โ‡ŒHgOAc2aqKf=2.7ร—108

Calculate the standard potential for the half-reaction

HgOAc2aq+2e-โ‡ŒHgl+2OAc-

(a) Calculate the standard potential for the reaction

For Ag3AsO4,Ksp=1.2ร—10-22

(b) Give a schematic representation of a cell with a silver indicator electrode and an SCE as reference that could be used for determining AsO43-.
(c) Derive an equation that relates the measured potential of the cell in (b) to (assume that the junction potential is zero).
(d) Calculate the pAsO4 of a solution that is saturated with and contained in the cell described in (b) if the resulting potential is 0.193 .

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