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Calculate the accelerating voltage that would be required to direct singly charged ions of mass 5000 through an instrument that is identical to the one described in Example 20-4.

Short Answer

Expert verified

The required accelerating voltage is 8.95 V.

Step by step solution

01

given

Given

B = 0.240 T
e= 1.60 x 10-19
r= 12.7 cm,
z= +1
m= 5000g/ mol

02

Explanation

The accelerating voltage can be calculated by:
V=B2r2ez2m.....1

Where,
B= the magnetic field strength is
r= radius of the curvature
e= electronic charge
m= mass
z= charge and
V= accelerating voltage

Now substitute values in equation (1)

Now substitute Values
B = 0.240 T
e= 1.60 x 10-19
r= 12.7 cm,
z= +1
m= 5000g/ mol

V=(0.240T)2(12.7cm)21.60×10-19C(+1)2(5000g/mol)=0.240T×1Vssmm21T212.7cm×1m100cm21.60×10-19C(1)25000gmol×1mol6.02×1023ions×1kg1g=0.2401Vs/m22(0.127m)21.60×10-19C28.306×10-24kg/ion×1V1(Vs)2C2m2kg=8.95V

So the accelerating voltage required is 8.95 V.

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Most popular questions from this chapter

On page 259a qualitative discussion described how a positive ion would behave in the xz plane (positive dc potential plane) of a quadrupole mass filter. Construct a similar argument for the behavior of positive ions in the yz plane (negative dc potential plane).

Calculate the ratio of the (M+2)+to M+and the (M+4)+to M+peak heights for

(a)C10H6Br2, (b)C3H7ClBrand (c)C6H4Cl2.

Discuss the differences between quadrupole ion-trap mass spectrometers and Fourier transform ICR mass spectrometers.

Figure 20-29(page 536) shows the mass spectrum of the same compound from an EI source and a CI source.

a. Which mass spectrum would be best for determining the molecular mass of the compound? Why?

b. Which mass spectrum would be best for determining the chemical structure? Why?

c. The EI source was a pulsed source used with a TOF mass analyzer. If the flight tube were 1.0m long and the accelerating voltage were 3000V, what would the flight time be for the ion at m/z=58?

d. For two ions of m/z values m1zand localid="1646035174939" m2z, derive an equation for the difference in flight times tFas a function of the two masses, the charges, and the accelerating voltage.

e. For the same TOF analyzer as in part (c), calculate the difference in flight times between ions of m1/zand m2/z

f. To get more structural information, the compound of Figure 20-27was subjected to tandem mass spectrometry. Which ionization source, EI or CI, would be most suitable for this purpose? Why?

g. Using the ionization source chosen in part (f), describe the types of mass spectra that could be obtained from an MS/MS experiment by:

1. holding the first mass analyzer constant and scanning the second analyzer.

2. scanning both analyzers with a small m/z offset between them.

3. scanning the first analyzer while holding the second analyzer constant.

4. scanning the second mass analyzer for every mass selected by the first analyzer.

In your answer, use features of the mass spectrum of Figure 20-29 to illustrate your description.

How do the spectra for electron-impact, field ionization, and chemical ionization sources differ from one another?

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