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A monochromator with a focal length of 0.75mwas equipped with an echellette grating with 3000blazes per millimeter.

(a) Calculate the reciprocal linear dispersion of the instrument for first-order spectra.

(b) If localid="1646643497497" 2.0cmof the grating were illuminated, what is the first-order resolving power of the monochromator?

(c) At approximatelylocalid="1646643508082" 400nm, what minimum wavelength difference could in theory be completely resolved by the instrument?

Short Answer

Expert verified

a)0.44nm/mmb)6×104c)200nm

Step by step solution

01

Given information

f=0.75m3000blaze/mmb)grating=2cmc)𝜆=400nm

02

Part a) Step 1: Calculation

Formula for e the reciprocal linear dispersion is

D-1=dnf

Putting values

localid="1646643603007" n=1D-1=(1mm3000blazes/mm)1×0.75mD-1=(1mm3000blazes/mm×106nmmm)1×0.75m×(103mmm)D-1=0.44nm/mm

03

Part b) Step 1: Calculations

Formula for resolving power of the monochromator is

R=nN

Putting values in formula

localid="1646643626931" R=1×3000blazes/mm×2cm×10mm/cmR=60000R=6×104

04

Part c) Step 1: Calculations

Formula for wavelength difference is

𝜆diff=12(𝜆max-𝜆min)

Putting values in formula

localid="1646643644855" 𝜆diff=12(400nm)𝜆diff=200nm

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Most popular questions from this chapter

With the aid of Figures 7-2 and 7-3, suggest instrument components and materials for constructing an instrument that would be well suited for

(a) the investigation of the fine structure of absorption bands in the region of 450 to 750 nm.

(b) obtaining absorption spectra in the far IR (20 to 50 μm).

(c) a portable device for determining the iron content of natural water based on the absorption of radiation by the red Fe(SCN)21 complex.

(d) the routine determination of nitrobenzene in air samples based on its absorption peak at 11.8 μm.

(e) determining the wavelengths of flame emission lines for metallic elements in the region from 200 to 780 nm.

(f) spectroscopic studies in the vacuum UV region.

(g) spectroscopic studies in the near IR.

For a grating, how many lines per millimeter would be required for the first-order diffraction line for 𝛌=400nmto be observed at a reflection angle of 7°when the angle of incidence is45°?

Relationships described in Problems 7.3and 7.4may be of help in solving the following.

(a) Calculate the wavelength of maximum emission of a tungsten filament bulb operated at the usual temperature of localid="1646640900138" 2870Kand at a temperature of localid="1646640967506" 3750K.

(b) Calculate the total energy output of the bulb in terms of localid="1646640979854" W/cm2.

A Michelson interferometer had a mirror velocity of 2.75cm/s. What would be the frequency of the interferogram for

(a) UV radiation of 350nm

(b) visible radiation of 575nm

(c) IR radiation of 5.5μm

(d) IR radiation of 25μm

Stefan’s law states that the total energy Etemitted by a blackbody per unit time and per unit area is given by role="math" localid="1646212237003" Et=αT4, where a has a value of 5.69×10-8Wm-2K-4. Calculate the total energy output inW/m2 for each of the blackbodies described in Problem 7.3.

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