Chapter 14: Q. 14.3 (page 353)
Sketch a photometric titration curve for the titration of with . What color radiation should be used for this titration? Explain.
Short Answer
The graph is,
Chapter 14: Q. 14.3 (page 353)
Sketch a photometric titration curve for the titration of with . What color radiation should be used for this titration? Explain.
The graph is,
All the tools & learning materials you need for study success - in one app.
Get started for freeThe chelate CuA22- exhibits maximum absorption at 480 nm. When the chelating reagent is present in at least a tenfold excess, the absorbance depends only on the analytical concentration of Cu(II) and conforms to Beerโs law over a wide range. A solution in which the analytical concentration of Cu2+ is 2.15 x 10-4 M and that for A2- is 9.00 x 10-3 M has an absorbance of 0.759 when measured in a 1.00-cm cell at 480 nm. A solution in which the analytical concentrations of Cu2+ and A2- are 2.15 x 10-4 M and 4.00 x 10-4 M, respectively, has an absorbance of 0.654 when measured under the same conditions. Use this information to calculate the formation constant Kffor the process
The accompanying data (cells) were obtained for the spectrophotometric titration of of Pd(II) with data-custom-editor="chemistry" Nitroso R (O. W. Rollins and M. M. Oldham, Anal. Chem., 1971, 43, 262, DOI: 10.1021/ac60297a026).
Calculate the concentration of the Pd(II) solution, given that the ligand-to-cation ratio in the colored product is 2:1.
A simultaneous determination for cobalt and nickel can be based on absorption by their respective 8-hydroxyquinolinol complexes. Molar absorptivities corresponding to their absorption maxima are given below:-
Calculate the molar concentration of nickel and cobalt in each of the following solutions using the following data: Absorbance, A (1.00-cm cells) Solution 365 nm 700 nm (a) 0.349 0.022 (b) 0.792 0.081
A 0.4740-g pesticide sample was decomposed by wet ashing and then diluted to 200.0 mL in a volumetric flask. The analysis was completed by treating aliquots of this solution as indicated.
Calculate the percentage of copper in the sample.
The enzyme monoamine oxidase catalyzes the oxidation of amines to aldehydes. For tryptamine, Km for the enzyme is 4.0 x 10 -4 M and at pH 8. Find the concentration of a solution of tryptamine that reacts at a rate of 0.12 ฮผm/min in the presence of monoamine oxidase under the
above conditions. Assume that [tryptamine]
What do you think about this solution?
We value your feedback to improve our textbook solutions.