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Radiation leaves a source at a natural frequency of (a) 9.10 x 1013Hz. What is the wavenumber corresponding to this frequency? If a Michelson interferometer has a mirror velocity of 1.00 cm/s, what will the frequency be at the transducer. Find the wavenumber at the source and frequency at the transducer for source radiation of

(b) 9.20 x 1013Hz and

(c) 9.30 x 1013 Hz.

Short Answer

Expert verified

a) Wavenumber at the given frequency is 3.03 x 103cm-1 and frequency of the transducer is 6.07 kHz.
b) Wavenumber at the given frequency is 3.07x 103cm-1 and frequency of the transducer is 6.13 kHz

c) Wavenumber at the given frequency is 3.10x 103cm-1 and frequency of the transducer is 6.20 kHz

Step by step solution

01

Concept

Frequency number of the occurrences of a particular event in a unit time. Wave number is a unit of frequency, often used in atomic, molecular, and nuclear spectroscopy.

The absorption maximum is given as :
v¯=12πckμ
Where c is the velocity of light

The frequency is given by

f=2vMv¯(II)
Where the
f=frequency
vM=the constant and
v¯=wavenumber

Substitute role="math" localid="1645888139139" v=12πkμ in Equation (I), we get\

v¯=vc(III)
Substitute for role="math" localid="1645888210654" v¯=vcin Equation (II), we get
f=2vMvc......(IV)

02

Part(a) Step 1- Given 

Given natural frequency is 9.1x1013 Hz.

Mirror velocity is 1 cm/sec.

Find the wavenumber at the source and frequency at the transducer

03

2- Part(a) Step2-Explanation.

Substitute9.1x1013 Hz and c=1010 cm/sec in equation (III),

V¯=9.10×1013Hz3×1010cms-1=9.103×103cm-1=3.03×103cm-1

Use this wave number and vM = 1 cm/sec in the equation (IV),

f=21.00cms-19.10×1013Hz3.00×1010cms-1=6.07×103s-11kHz103s-1=6.07kHz

04

Part(b) Step 1- Given 

Given natural frequency is 9.20 x 1013 Hz.

Mirror velocity is 1 cm/sec.

Find the wavenumber at the source and frequency at the transducer

05

Part(b) Step 2 - Explanation

Substitute 9.20 x 1013 Hz and c=1010 cm/sec in equation (III),

v¯=9.20×1013Hz3×1010cms-1=9.203×103cm-1=3.07×103cm-1

Use this wave number and vM = 1 cm/sec in the equation (IV),

f=21.00cms-19.20×1013Hz3.00×1010cms-1=6.13×103s-11kHz103s-1=6.13kHz

06

Part(c) Step1 Given: 

Given natural frequency is 9.30 x 1013 Hz.

Mirror velocity is 1 cm/sec.

Find the wavenumber at the source and frequency at the transducer

07

Part(c) Step2 -Explanation

Substitute 9.30 x 1013 Hz and c=1010 cm/sec in equation (III),

v¯=9.30×1013Hz3×1010cms-1=9.303×103cm-1=3.10×103cm-1

Use this wave number and vM = 1 cm/sec in the equation (IV),

f=21.00cms-19.30×1013Hz3.00×1010cms-1=6.20×103s-11kHz103s-1=6.20kHz

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Most popular questions from this chapter

The wavelength of the fundamental O-Hstretching vibration is about 3.0µm. What is the approximate wavenumber and wavelength of the first overtone band for the O-Hstretch?

Gaseous HCl exhibits an IR absorption at 2890cm-1due to the hydrogen-chlorine stretching vibration.

(a) Calculate the force constant for the bond.

(b) Calculate the wavenumber of the absorption band for DCl assuming the force constant is the same as that calculated in part (a).

Sulfur dioxide is a nonlinear molecule. How many vibrational modes will this compound have? How many IR absorption bands would sulfur dioxide be expected to have?

(a) The IR spectrum of gaseous N2O shows three strong absorption bands at 2224 cm-1, 1285 cm-1, and 2089 cm-1. In addition two quite weak bands are observed at 2563 cm-1 and 2798 cm-1. It is known that N2O is a linear molecule, but assume it is not known whether the structure is N-N-O or N-O-N. Use the IR data to decide between the two structures. What vibrations can be assigned to the strong absorption bands? What are possible causes of the weak absorptions?
(b) The IR spectrum of HCN shows three strong absorption bands at 3312 cm-1, 2089 cm-1, and 712 cm-1. From this information alone, can you deduce whether HCN is linear or nonlinear? Assuming that HCN is linear, assign vibrations to the three absorption bands.
(c) How many fundamental vibrational modes are expected for BF3? Which of these are expected to be IR active? Why? Sketch the vibrations.
(d) How many fundamental vibrational modes would you predict for (1) methane, (2) benzene, (3) toluene, (4) ethylene, and (5) carbon tetrachloride?

What are the major advantages of an FTIR spectrometer compared with a dispersive instrument?

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