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In a particular trace analysis via FTIR, a set of sixteen interferograms was collected. The signal-to-noise ratio (S/N) associated with a particular spectral peak was approximately 4:1. How many interferograms would have to be collected and averaged if the goal is to obtain an S/N = 20:1?

Short Answer

Expert verified

The number of interferograms would have to be collected and averaged if the goal is to obtain an S/N = 20:1 is 400.

Step by step solution

01

Step 1. Given information

In a particular trace analysis via FTIR, a set of sixteen interferograms was collected. The signal-to-noise ratio (S/N) associated with a particular spectral peak was approximately 4:1. The number of interferograms that have to be collected and averaged if the goal is to obtain anS/N=20:1.

02

Step 2. Explanation

A set of sixteen interferometers is collected, the signal to noise ratio is 4: 1.

The expression for the signal to noise ratio after n repetitions is given by:

SNn=k(n)1/2(I)

Substitute n=16, we get

SN16=k(16)1/2.(II)

For n we will have

SNn=k(n)1/2(III)

Divide the Equation (III) by Equation (II), we get

sNnsN16=k(n)1/2k(16)1/2..(IV)

Substitute SNn=20

and SN16=4

we get

204=k(n)1/2k(16)1/2

Solve for n,

we get n=400.

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Most popular questions from this chapter

(a) The IR spectrum of gaseous N2O shows three strong absorption bands at 2224 cm-1, 1285 cm-1, and 2089 cm-1. In addition two quite weak bands are observed at 2563 cm-1 and 2798 cm-1. It is known that N2O is a linear molecule, but assume it is not known whether the structure is N-N-O or N-O-N. Use the IR data to decide between the two structures. What vibrations can be assigned to the strong absorption bands? What are possible causes of the weak absorptions?
(b) The IR spectrum of HCN shows three strong absorption bands at 3312 cm-1, 2089 cm-1, and 712 cm-1. From this information alone, can you deduce whether HCN is linear or nonlinear? Assuming that HCN is linear, assign vibrations to the three absorption bands.
(c) How many fundamental vibrational modes are expected for BF3? Which of these are expected to be IR active? Why? Sketch the vibrations.
(d) How many fundamental vibrational modes would you predict for (1) methane, (2) benzene, (3) toluene, (4) ethylene, and (5) carbon tetrachloride?

What length of mirror drive in an FTIR spectrometer would be required to provide a resolution of (a) 0.010 cm-1, (b) 0.50 cm-1, and (c) 2.0 cm-1?

Radiation leaves a source at a natural frequency of (a) 9.10 x 1013Hz. What is the wavenumber corresponding to this frequency? If a Michelson interferometer has a mirror velocity of 1.00 cm/s, what will the frequency be at the transducer. Find the wavenumber at the source and frequency at the transducer for source radiation of

(b) 9.20 x 1013Hz and

(c) 9.30 x 1013 Hz.

Calculate the absorption frequency corresponding to the -C-Hstretching vibration treating the group as a simple diatomic C-Hmolecule with a force constant of k=5×102N/m. Compare the calculated value with the range found in correlation charts (such as the one shown in Figure 17-6). Repeat the calculation for the deuterated bond.

It was stated that at room temperature (25°C) the majority of molecules are in the ground vibrational energy level (v = 0).
(a) Use the Boltzmann equation (Equation 8-1) to calculate the excited-state and ground-state population ratios for HCl: N(v =1)/N(v = 0). The fundamental vibrational frequency of HCl occurs at 2885 cm-1.

(b) Use the results of part (a) to find N(v = 2)/N(v = 0)

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