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For producing the effective collisions, the colliding molecules must possess a. Energy equal to activation energy b. Energy equal to or greater than threshold energy c. Proper orientation d. Energy greater than threshold energy

Short Answer

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The colliding molecules must possess energy equal to or greater than threshold energy and proper orientation to produce effective collisions.

Step by step solution

01

Understand Effective Collisions

Effective collisions in a chemical reaction are defined as those that result in the formation of products. For a collision to be effective, certain conditions must be met: the colliding particles need to have sufficient energy and the correct orientation when they collide.
02

Know the Requirements for Effective Collisions

There are two main requirements for effective collisions: (1) The particles must have energy equal to or greater than the activation energy, which is the minimum energy required to start a reaction; (2) The particles must have the proper orientation during the collision such that the relevant parts of the molecules can interact to form products.
03

Analyze the Given Options

Let's go through the given options: - a) Energy equal to activation energy: This is necessary, but often particles need slightly more than just the exact activation energy due to real-world dynamics. - b) Energy equal to or greater than threshold energy: The threshold energy is equivalent to activation energy in this context, so this option fits well. - c) Proper orientation: Correct, as orientation is critical for an effective collision. - d) Energy greater than threshold energy: This is usually required to overcome not just the activation energy but to account for additional dynamics too.
04

Identify the Correct Answers

From the analysis, both options b) Energy equal to or greater than threshold energy and c) Proper orientation are essential requirements for effective collisions. Option d) Energy greater than threshold energy is also relevant since excess energy helps ensure the reaction can proceed, making b) and d) part of the correct answers.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Activation Energy Unveiled
Activation energy is a key concept in understanding chemical reactions. It is defined as the minimum amount of energy that the reacting species must possess for a reaction to occur. Imagine activation energy as a barrier that reactants must overcome to transform into products. Without enough energy, the molecules will not have the ability to start the transformation process.

This minimum energy ensures that only the high-energy collisions lead to chemical changes. It's like needing a specific key to unlock a door. Just any key (or in this case, energy) won't do. Only those collisions with energy equal to or greater than the activation energy will be successful in creating a reaction.

To illustrate this further:
  • Low energy collisions: Insufficient to overcome activation energy.
  • Exactly at activation energy: Right on the edge of success, often needing a touch more.
  • Greater than activation energy: Ideal for overcoming the barrier efficiently.
Understanding activation energy helps explain why some reactions require heat or light to get started—these sources provide the additional energy needed to reach or exceed the activation energy.
Understanding Threshold Energy
Threshold energy is closely linked to activation energy and often used interchangeably, but with slight nuances. It refers to the specific energy level required for a successful reaction or product formation to occur. Think of it as a milestone or a target energy that reactants need to aim for.

In the context of chemical reactions, threshold energy represents the baseline energy needed for colliding particles to potentially produce a product. More than just crossing a barrier, threshold energy sets the stage for effective collisions by ensuring that reactant molecules have enough energy to rearrange into new structures.

Key points about threshold energy:
  • Baseline energy requirement: Sets the minimum energy level for reaction possibility.
  • Equivalent to activation energy: In many practical scenarios, they coincide.
  • Beyond the threshold: Helps in accounting for kinetic energy distribution and external influences.
Understanding threshold energy, therefore, clarifies why reactions have specific energy requirements to proceed and highlights the importance of energy in dictating reaction feasibility.
The Role of Molecular Orientation
The concept of molecular orientation is a fascinating aspect of chemistry that affects how reactions proceed. It's not just about having enough energy; the molecules need to be aligned properly for a reaction to occur.

Imagine two puzzle pieces coming together: they not only need to fit (energy requirement) but also need to be rotated correctly to slot into place (orientation). Similarly, for molecules to interact successfully and form products, their orientation during collision plays a crucial role.

Here's why molecular orientation matters:
  • Correct parts must interact: Only when the reactive parts of molecules face each other properly can they form bonds.
  • Maximizes reaction efficiency: Proper orientation increases the chance of a successful collision.
  • Catalysts and enzymes: Often help in aligning molecules suitably for reactions.
Understanding molecular orientation provides insight into catalysis and enzyme action, showing how they often work by simply orienting reactive sites correctly, allowing molecules to react more efficiently.

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Most popular questions from this chapter

In the following question two statements Assertion (A) and Reason (R) are given Mark. a. If \(\mathrm{A}\) and \(\mathrm{R}\) both are correct and \(\mathrm{R}\) is the correct explanation of \(\mathrm{A}\); b. If \(A\) and \(R\) both are correct but \(R\) is not the correct explanation of \(\mathrm{A}\); c. \(\mathrm{A}\) is true but \(\mathrm{R}\) is false; d. \(\mathrm{A}\) is false but \(\mathrm{R}\) is true, e. \(\mathrm{A}\) and \(\mathrm{R}\) both are false. (A): If order with respect to species involved in any reaction is not equals to the stoichiometric coefficient of that species in the reaction then reaction must be an elementary reaction. (R): In an elementary reaction the order with respect to species involved is equal to the stoichiometric coefficients.

In a hypothetical reaction given below $$ 2 \mathrm{XY}_{2}(\mathrm{aq})+2 \mathrm{Z}^{-}(\mathrm{aq}) \rightarrow $$ (Excess) $$ 2 \mathrm{XY}_{2}^{-}(\mathrm{aq})+\mathrm{Z}_{2}(\mathrm{aq}) $$ \(\mathrm{XY}_{2}\) oxidizes \(\mathrm{Z}\) - ion in aqueous solution to \(\mathrm{Z}_{2}\) and gets reduced to \(\mathrm{XY}_{2}-\) The order of the reaction with respect to \(\mathrm{XY}_{2}\) as concentration of \(Z\) - is essentially constant. Rate \(=\mathrm{k}\left[\mathrm{XY}_{2}\right]^{\mathrm{m}}\) Given below the time and concentration of \(\mathrm{XY}_{2}\) taken (s) Time \(\left(\mathrm{XY}_{2}\right) \mathrm{M}\) \(0.00\) \(4.75 \times 10^{-4}\) \(1.00\) \(4.30 \times 10^{-4}\) \(2.00\) \(3.83 \times 10^{-4}\) The order with respect to \(\mathrm{XY}_{2}\) is a. 0 b. 1 c. 2 d. 3

For a first order reaction, which is/are correct here? a. The time taken for the completion of \(75 \%\) reaction is twice the \(t_{1 / 2}\) of the reaction b. The degree of dissociation is equal to \(1-\mathrm{e}^{-k t}\). c. A plot of reciprocal concentration of the reactant versus time gives a straight line d. The pre-exponential factor in the Arrhenius equation has the dimension of time, \(\mathrm{T}^{-1}\).

The first order isomerisation reaction: Cyclopropane \(\rightarrow\) propene, has a rate constant of \(1.10 \times 10^{-4} \mathrm{~s}^{-1}\) at \(470^{\circ} \mathrm{C}\) and an activation energy of \(264 \mathrm{~kJ} / \mathrm{mol}\). What is the temperature of the reaction when the rate constant is equal to \(4.36 \times 10^{-3} \mathrm{~s}^{-1}\) ? a. \(240^{\circ} \mathrm{C}\) b. \(150^{\circ} \mathrm{C}\) c. \(540^{\circ} \mathrm{C}\) d. \(450^{\circ} \mathrm{C}\)

In Arrhenius equation, \(\mathrm{k}=\mathrm{A} \exp (-\mathrm{Ea} / \mathrm{RT})\). A may be regarded as the rate constant at a. Very high temperature b. Very low temperature c. High activation energy d. Zero activation energy

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