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Normalize the total energy eigenfunction for the rectangular two-dimensional box, \\[ \psi_{n_{n} n_{y}}(x, y)=N \sin \left(\frac{n_{x} \pi x}{a}\right) \sin \left(\frac{n_{y} \pi y}{b}\right) \\] in the interval \(0 \leq x \leq a, 0 \leq y \leq b\)

Short Answer

Expert verified
The normalized wavefunction for the given rectangular two-dimensional box is: \[ \psi_{n_x n_y}(x, y) = \frac{2}{\sqrt{ab}} \sin\left( \frac{n_x \pi x}{a} \right) \sin\left( \frac{n_y \pi y}{b} \right) \]

Step by step solution

01

Square the wavefunction and multiply by normalization constant squared

First, we need to square the given wavefunction and multiply it with the normalization constant squared, N^2: \[ \left| \psi_{n_x n_y}(x, y) \right|^2 = N^2 \sin^2\left(\frac{n_x \pi x}{a}\right) \sin^2\left(\frac{n_y \pi y}{b}\right) \]
02

Integrate the squared wavefunction

Now, we integrate the squared wavefunction with respect to x from \(0\) to \(a\), and with respect to y from \(0\) to \(b\): \[ \int_{0}^{a} \int_{0}^{b} N^2 \sin^2\left(\frac{n_x \pi x}{a}\right) \sin^2\left(\frac{n_y \pi y}{b}\right) dx dy \] Let's solve the integral: \[ N^2 \int_{0}^{a} \sin^2\left(\frac{n_x \pi x}{a}\right) dx \int_{0}^{b} \sin^2\left(\frac{n_y \pi y}{b}\right) dy \] Using the following integral: \[ \int_{0}^{L} \sin^2\left(\frac{m \pi x}{L}\right)dx = \frac{L}{2} \] We obtain: \[ N^2 \frac{a}{2} \frac{b}{2} = N^2 \frac{ab}{4} \]
03

Solve for the normalization constant N

Now, we will set the previous result equal to 1 and solve for N: \[ N^2 \frac{ab}{4} = 1 \] \[ N^2 = \frac{4}{ab} \] Taking the square root of both sides, we find the normalization constant, N: \[ N = \frac{2}{\sqrt{ab}} \] #Solution# The normalized wavefunction for the given rectangular two-dimensional box is: \[ \psi_{n_x n_y}(x, y) = \frac{2}{\sqrt{ab}} \sin\left( \frac{n_x \pi x}{a} \right) \sin\left( \frac{n_y \pi y}{b} \right) \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that describes the physical properties of nature at the scale of atoms and subatomic particles. It is a mathematical framework for the dual particle-wave nature of these particles, where the behavior of quantum systems is fundamentally different from classical systems due to the quantum nature of the matter. One of the core components of quantum mechanics is the quantization of energy, momentum and angular momentum, and the discretization of certain physical properties.

Quantum mechanics often seems counterintuitive, challenging our classical notions of reality. However, it's indispensable for understanding how the universe works on the smallest scales and has led to technologies such as semiconductors, lasers, and MRI machines.
Wavefunction
The wavefunction is a central concept in quantum mechanics representing the quantum state of a particle or system of particles. It is a mathematical function that encodes the probabilities of the outcomes of measurements made on the system, such as the probability of finding a particle in a certain position or with a certain momentum.

The properties of wavefunctions are governed by Schrödinger's equation. Importantly, wavefunctions must be normalized, meaning that their squared modulus, representing probability density, must integrate to one across all space. This is to ensure that the probability of finding the particle somewhere in space is certain.
Rectangular Two-Dimensional Box
In quantum mechanics, a rectangular two-dimensional box is a theoretical model used to simplify the complex reality of particle confinement. This model is a part of the 'particle in a box' problems, which are idealized systems where particles are free to move within a defined area or volume but cannot escape it - a concept that parallels the behavior of electrons in quantum wells.

The boundaries of the box are considered to be infinitely high potential walls, which the particles cannot penetrate. Solutions to this model involve wavefunctions that satisfy the model's boundary conditions - zero at the walls and continuous inside the box. They form standing waves, displaying the characteristic quantization of energy levels within the box.
Eigenfunctions
Eigenfunctions are a key concept when dealing with operators in quantum mechanics. An eigenfunction of an operator is a non-zero function that, when the operator is applied to it, results in a scalar multiple of the original function. This scalar is known as the eigenvalue and is often associated with a measurable physical property, such as energy or momentum.

In the context of the rectangular two-dimensional box problem, the eigenfunctions describe the permissible wavefunctions that satisfy both the Schrödinger equation and the boundary conditions of the system. These wavefunctions can only take specific forms that lead to quantized energy levels, and each wavefunction corresponds to a particular energy state of the particle trapped within the box.

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Most popular questions from this chapter

Two wave functions are distinguishable if they lead to a different probability density. Which of the following wave functions are distinguishable from \(\sin k x ?\) a. \(\left(e^{i k x}-e^{-i k x}\right) / 2\) b. \(e^{i \theta} \sin k x, \theta\) a constant c. \(\cos (k x-\pi / 2)\) d. \(i \cos (k x+\pi / 2)(\sin \theta+i \cos \theta)\left(-\frac{\sqrt{2}}{2}+i \frac{\sqrt{2}}{2}\right)\) \(\theta\) is a constant

Generally, the quantization of translational motion is not significant for atoms because of their mass. However, this conclusion depends on the dimensions of the space to which they are confined. Zeolites are structures with small pores that we describe by a cube with edge length 1 nm. Calculate the energy of a \(\mathrm{H}_{2}\) molecule with \(n_{x}=n_{y}=n_{z}=10 .\) Compare this energy to \(k_{B} T\) at \(T=300 .\) K. Is a classical or a quantum description appropriate?

Calculate the probability that a particle in a onedimensional box of length \(a\) is found between \(0.32 a\) and \(0.35 a\) when it is described by the following wave functions: a. \(\sqrt{\frac{2}{a}} \sin \left(\frac{\pi x}{a}\right)\) b. \(\sqrt{\frac{2}{a}} \sin \left(\frac{3 \pi x}{a}\right)\) What would you expect for a classical particle? Compare your results for (a) and (b) with the classical result.

Derive an equation for the probability that a particle characterized by the quantum number \(n\) is in the first \(25 \%\) \((0 \leq x \leq 0.25 a)\) of an infinite depth box. Show that this probability approaches the classical limit as \(n \rightarrow \infty\)

Suppose that the wave function for a system can be written as \\[ \psi(x)=\frac{\sqrt{3}}{4} \phi_{1}(x)+\frac{\sqrt{3}}{2 \sqrt{2}} \phi_{2}(x)+\frac{2+\sqrt{3} i}{4} \phi_{3}(x) \\] and that \(\phi_{1}(x), \phi_{2}(x),\) and \(\phi_{3}(x)\) are normalized eigenfunctions of the operator \(\hat{E}_{\text {kinetic}}\) with eigenvalues \(E_{1}, 2 E_{1},\) and \(4 E_{1},\) respectively. a. Verify that \(\psi(x)\) is normalized. b. What are the possible values that you could obtain in measuring the kinetic energy on identically prepared systems? c. What is the probability of measuring each of these eigenvalues? d. What is the average value of \(E_{k \text {inetic}}\) that you would obtain from a large number of measurements?

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