Chapter 20: Problem 12
What general kind of reaction does ATP carry out?
Short Answer
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 20: Problem 12
What general kind of reaction does ATP carry out?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeLeucine is biosynthesized from \(\alpha\) -ketoisocaproate, which is itself formed from \(\alpha\) -ketoisovalerate by a multistep route that involves: (1) reaction of \(\alpha\) -ketoisocaproate with acetyl CoA in an aldol-like reaction (2) hydrolysis of the thioester (3) dehydration by an E1cB mechanism (4) hydration by a conjugate addition reaction (5) oxidation of an alcohol to a ketone (6) decarboxylation of a \(\beta\) -keto acid Show the steps in the biosynthesis, and propose a mechanism for each.
In the oxidative deamination of glutamate, is the hydride ion transferred to the Re face or the \(S\) face of \(\mathrm{NAD}^{+} ?\) (Review Section \(5.11 .\) )
The final step in lysine biosynthesis is decarboxylation of meso2,6-diaminopimelate. The reaction requires PLP as cofactor and occurs through the usual PLP-amino acid imine. Propose a mechanism.
Draw the structure of adenosine \(5^{\prime}\) -monophosphate (AMP), an intermediate in numerous biochemical pathways.
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