Chapter 29: Q29-35E (page 1012)
Draw the structure of adenosine 5’-monophosphate (AMP), an intermediate in some biochemical pathways.
Short Answer
The structure of adenosine 5’-monophosphate (AMP) is,
Chapter 29: Q29-35E (page 1012)
Draw the structure of adenosine 5’-monophosphate (AMP), an intermediate in some biochemical pathways.
The structure of adenosine 5’-monophosphate (AMP) is,
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Get started for freeThe initial reaction in Problem 29-52, conversion of two molecules of acetyl CoA to one molecule of acetoacetyl CoA, is a Claisen reaction. Assuming that there is a base present, show the mechanism of the reaction.
In glycerol metabolism, the oxidation of sn-glycerol 3-phosphate to give dihydroxyacetone phosphate is catalyzed by sn-glycerol-3-phosphate dehydrogenase, with NAD1 as a cofactor. The reaction is stereospecific, occurring exclusively on the Re face of the nicotinamide ring. Which hydrogen in the NADH product comes from sn-glycerol 3-phosphate? Does it have pro-R or pro-S stereochemistry?
PROBLEM 29-5Evidence for the role of acetate in fatty-acid biosynthesis comes from isotope labelling experiments. If acetate labelled within the methyl group () were incorporated into fatty acids, at what positions in the fatty-acid chain would you expect thelabel to appear?
What general kind of reaction does FAD carry out?
What enzyme cofactor is associated with each of the following kinds of reactions?
(a) Transamination
(b) Carboxylation of a ketone
(c) Decarboxylation of an
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