Chapter 31: 21E (page 1054)
Draw a three-dimensional representation of segments of the following polymers:
(a) Syndiotactic polyacrylonitrile
(b) Atactic poly (methyl methacrylate)
(c) Isotactic poly (vinyl chloride)
Chapter 31: 21E (page 1054)
Draw a three-dimensional representation of segments of the following polymers:
(a) Syndiotactic polyacrylonitrile
(b) Atactic poly (methyl methacrylate)
(c) Isotactic poly (vinyl chloride)
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Get started for freeMelmac, a thermosetting resin often used to make plastic dishes, is prepared by heating melamine with formaldehyde. Look at the structure of Bakelite shown in Section 31-6, and then propose a structure for Melmac.
Polymers such as polypropylene contain a large number of chirality centers. Would you therefore expect samples of isotactic, syndiotactic, or atactic polypropylene to rotate plane-polarized light? Explain.
Nomex, a polyamide used in such applications as fire-retardant clothing, is prepared by reaction of 1,3-benzenediamine with 1,3-benzenedicarbonyl chloride. Show the structure of Nomex.
Poly (vinyl butyral) is used as the plastic laminate in the preparation of automobile windshield safety glass. How would you synthesize this polymer?
Irradiation of poly (1,3-butadiene), followed by the addition of styrene, yields a graft copolymer that is used to make rubber soles for shoes. Draw the structure of a representative segment of this styrene-butadiene graft copolymer.
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