Chapter 31: 21E (page 1054)
Draw a three-dimensional representation of segments of the following polymers:
(a) Syndiotactic polyacrylonitrile
(b) Atactic poly (methyl methacrylate)
(c) Isotactic poly (vinyl chloride)
Chapter 31: 21E (page 1054)
Draw a three-dimensional representation of segments of the following polymers:
(a) Syndiotactic polyacrylonitrile
(b) Atactic poly (methyl methacrylate)
(c) Isotactic poly (vinyl chloride)
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Get started for freeVinylidene chloride, H2C = CHCl, does not polymerize in isotactic, syndiotactic, and atactic forms. Explain.
The smoking salons of the Hindenburg and other hydrogen-filled dirigibles of the 1930s were insulated with ureaโformaldehyde polymer foams. The structure of this polymer is highly cross-linked, like that of Bakelite (Section 31-6). Propose a structure.
Polymers such as polypropylene contain a large number of chirality centers. Would you therefore expect samples of isotactic, syndiotactic, or atactic polypropylene to rotate plane-polarized light? Explain.
Order the following monomers concerning their expected reactivity toward anionic polymerization, and explain your answer:
H2C = CHCH3, H2C = CHC N, H2C = CH-C6H5
Show the mechanism of the nucleophilic addition reaction of an alcohol with an isocyanate to yield a urethane.
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