Chapter 13: Q13-25E (page 419)
How many absorptions would you expect the following compound tohave in its 1H and 13C NMR spectra?
Chapter 13: Q13-25E (page 419)
How many absorptions would you expect the following compound tohave in its 1H and 13C NMR spectra?
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Get started for freeLong-range coupling between protons more than two carbon atoms apart is sometimes observed when p bonds intervene. An example is found in 1-methoxy-1-buten-3-yne. Not only does the acetylenic proton, , couple with the vinylic proton , it also couples with the vinylic proton , four carbon atoms away. The data are:
Construct tree diagrams that account for the observed splitting patterns of ,, and .
How many kinds of electronically non-equivalent protons are present in each of the following compounds, and thus how many NMR absorptions might you expect in each?
How many absorptions would you expect to observe in the NMR
spectra of the following compounds?
(a) 1,1-Dimethylcyclohexane
(b) CH3CH2OCH3
(c) tert-Butylcyclohexane
(d) 3-Methyl-1-pentyne
(e) cis-1,2-Dimethylcyclohexane
(f) Cyclohexanone
A NMR spectrum of commercially available 2,4-pentanediol, shows five peaks at 23.3, 23.9, 46.5, 64.8, and 68.1 d. Explain.
How many types of non-equivalent protons are present in each of the following molecules?
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