Chapter 13: Q13-25E (page 419)
How many absorptions would you expect the following compound tohave in its 1H and 13C NMR spectra?
Chapter 13: Q13-25E (page 419)
How many absorptions would you expect the following compound tohave in its 1H and 13C NMR spectra?
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Get started for freeThe following NMR peaks were recorded on a spectrometer operating at
200 MHz. Convert each into O1units.
(a) CH3CI; 1454Hz
(b) CHCI3; 610Hz
(c) CH3OH; 693Hz
(d) CH2CI2; 1060Hz
Calculate the amount of energy required to spin-flip a proton in a spectrometer operating at 300 MHz. Does increasing the spectrometer frequency from 200 to 300 MHz increase or decrease the amount of energy necessary for
resonance?
Propose a structure for compound C, which has = 86 in its mass spectrum, an IR absorption at 3400, and the following NMR spectral data:
Compound C Broadband-decoupled NMR: 30.2, 31.9, 61.8, 114.7, 138.4 d DEPT-90: 138.4 d DEPT-135: positive peak at 138.4 d; negative peaks at 30.2, 31.9, 61.8, 114.7 d
Question: Sketch what you might expect the1H and13C NMR spectra of the following compound to look like (green=Cl):
Propose structures for compounds that fit the following descriptions:
(a) A hydrocarbon with seven lines in its 13C NMR spectrum
(b) A six-carbon compound with only five lines in its 13C NMR spectrum
(c) A four-carbon compound with three lines in its 13C NMR spectrum
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