Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.
Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.
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Get started for freeThe proton NMR spectrum of a compound with the formula C7H12O2is
shown. The infrared spectrum displays a strong band at 1738 cm-1 and
a weak band at 1689 cm-1 . The normal carbon-13 and the DEPT experimental
results are tabulated. Draw the structure of this compound.
Question: The mass spectrum and NMR spectrum of a hydrocarbon are shown. Propose a structure for this hydrocarbon, and explain the spectral data.
The integrated 1H NMR spectrum of a compound of the formulais shown in Figure. Propose a structure.
Compound F, a hydrocarbon with = 96 in its mass spectrum, undergoes reaction with HBr to yield compound G. Propose structures for F and G, whose NMR spectral data are given below.
a. Compound F Broadband-decoupled NMR: 27.6, 29.3, 32.2, 132.4 d DEPT-90: 132.4 d DEPT-135: positive peak at 132.4 d; negative peaks at 27.6, 29.3, 32.2 d
b. Compound G Broadband-decoupled NMR: 25.1, 27.7, 39.9, 56.0 d DEPT-90: 56.0 d DEPT-135: positive peak at 56.0 d; negative peaks at 25.1, 27.7, 39.9 d
The following compounds all show a single line in their NMR spectra. List them in order of expected increasing chemical shift:
,cyclohexane ,,benzene
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