Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.
Chapter 13: Q 57P (page 419)
Question: The NMR spectra of compound A, , are shown. Propose a structure for A, and assign peaks in the spectra to your structure.
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Get started for freeEstimate the chemical shift of each carbon in the following molecule. Predict which carbons will appear in the DEPT-90 spectrum, which will give positive peaks in the DEPT-135 spectrum, and which will give negative peaks in the DEPT-135 spectrum.
Propose a structure for compound E, , which has the following NMR spectral data:
Compound E Broadband-decoupled NMR: 19.1, 28.0, 70.5, 129.0, 129.8, 165.8 DEPT-90: 28.0, 129.8 DEPT-135: positive peaks at 19.1, 28.0, 129.8 ; negative peaks at 70.5, 129.0
How many absorptions would you expect the following compound tohave in its 1H and 13C NMR spectra?
Is a nucleus that absorbs at 6.50 more shielded or less shielded than a nucleus that absorbs at 3.20 ? Does the nucleus that absorbs at 6.5 require a stronger applied field or a weaker applied field to come into resonance than the one that absorbs at 3.20 ?
How many kinds of electronically non-equivalent protons are present in each of the following compounds, and thus how many NMR absorptions might you expect in each?
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