Chapter 12: Q9P. (page 354)
Predict the products of the following polar reaction, a step in the citric acid cycle for food metabolism, by interpreting the flow of electrons indicated by the curved arrows:
Short Answer
Answer
Chapter 12: Q9P. (page 354)
Predict the products of the following polar reaction, a step in the citric acid cycle for food metabolism, by interpreting the flow of electrons indicated by the curved arrows:
Answer
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Get started for freeQuestion: Propose structures for compounds that meet the following descriptions:
(a)with IR absorptions at 3300 and 2150
(b)with a strong IR absorption at 3400
(c) with a strong IR absorption at 1715
(d) with IR absorptions at 1600 and 1500
The Favorskii reactioninvolves the treatment of an -bromo ketone with a base to yield a ring-contracted product. For example, the reaction of 2-bromocyclohexanone with aqueous NaOH yields cyclopentanecarboxylic acid. Propose a mechanism.
Draw structures corresponding to the following IUPAC names:
a)cis-1,2-Cyclohexanedicarboxylic acid
b) Hepatanedioic acid
c) 2-Hexen-4-ynoic acid
d) 4-Ethyl-2-propyloctanoic acid
e) 3-chlorophthalic acid
f) Triphenylacetic acid
g) 2-Cyclobutenecarbonitrile
h) m-Benzoylbenzonitrile
Grignard reagents undergo a general and very useful reaction with
ketones. Methylmagnesium bromide, for example, reacts with cyclohexanoneto yield a product with the formula C7H14O . What is the structure of this product if it has an IR absorption at 3400 cm-1 ?
Which is stronger, the C=O bond in an ester () or the C=O bond in a saturated ketone ()? Explain
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