Chapter 12: Q35c E (page 385)
Question: At what approximate positions might the following compounds show
IR absorptions?
(c)
Short Answer
(c) It shows two distinguished absorptions due to at 910-990,
at 1640-1680 and at 3020-3100.
Chapter 12: Q35c E (page 385)
Question: At what approximate positions might the following compounds show
IR absorptions?
(c)
(c) It shows two distinguished absorptions due to at 910-990,
at 1640-1680 and at 3020-3100.
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Get started for freeQuestion: By knowing the natural abundances of minor isotopes, it’s possible to
calculate the relative heights of and M+1 peaks. If 13C has a natural
abundance of 1.10%, what are the relative heights of the and
M+1 peaks in the mass spectrum of benzene, C6H6?
Question: At what approximate positions might the following compounds show
IR absorptions?
(b)
In light of the nitrogen rule mentioned in Problem 12-17, what is themolecular formula of pyridine, M+=79?
Ketones undergo a reduction when treated with sodium borohydride, NaBH4
. What is the structure of the compound produced by reaction
of 2-butanone with NaBH4 if it has an IR absorption at 3400 cm-1 and M+ = 74in the mass spectrum?
Question: Write molecular formulas for compounds that show the following molecular ions in their high-resolution mass spectra, assuming that C, H, N, and O might be present. The exact atomic masses are: 1.00783 , 12.00000 , 14.00307 , 15.99491 .
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