Chapter 12: Q11P (page 383)
Where might the following compound have IR absorptions?
Short Answer
Absorption bands seen at 2210-2260 cm-1 , 1690cm-1 and 1640-1680cm-1 .
Chapter 12: Q11P (page 383)
Where might the following compound have IR absorptions?
Absorption bands seen at 2210-2260 cm-1 , 1690cm-1 and 1640-1680cm-1 .
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Get started for freeNitriles, R - C = N , undergo a hydrolysis reaction when heated with
aqueous acid. What is the structure of the compound produced by hydrolysis of propanenitrile, CH3CH2C=N , if it has IR absorptions from 2500-3100cm-1 and at 1710cm-1 , and has M+ = 74?
Predict the product(s) and provide the mechanism for each reaction below. What does each mechanism have in common?
Propose structures for compounds that fit the following mass-spectraldata:
(a) A hydrocarbon with M+= 132
(b) A hydrocarbon with M+=166
(c) A hydrocarbon with M+= 84
Aprobarbital, a barbiturate once used in treating insomnia, is synthesized in three steps from diethyl malonate. Show how you would synthesize the necessary dialkylated intermediate, and then propose a mechanism for the reaction of this intermediate with urea to give aprobarbital.
Assuming that strong acids add to alkynes in the same manner as they add to alkenes, propose a mechanism for each of the following reactions:
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