Chapter 5: Q56 E_b. (page 148)
Identify the indicated faces in the following molecules as Re or Si:
(a)
(b)
Short Answer
(b)
Chapter 5: Q56 E_b. (page 148)
Identify the indicated faces in the following molecules as Re or Si:
(a)
(b)
(b)
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Get started for freeKetones react with sodium acetylide (the sodium salt of acetylene,) to give alcohols. For example, the reaction of sodium acetylide with 2-butanone yields 3-methyl-1-pentyn-3-ol
(a)Is the product chiral?
(b)Assuming that the reaction takes place with equal likelihood from both Reand Sifaces of the carbonyl group, is the product optically active? Explain.
Draw both cis- and trans-1,3-dimethyl cyclohexane in their more stable chair conformations.
(a) How many stereoisomers are there of cis-1,3-dimethyl cyclohexane, and how many of trans-1,3-dimethyl cyclohexane?
(b) Are any of the structures chiral?
(c) What are the stereochemical relationships among the various stereoisomers of 1,3-dimethyl cyclohexane?
Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each:
(a)
(b)
(c)
Question:Which of the following objects are chiral?
(a) Soda can
(b)Screwdriver
(c)Screw
(d)Shoe
Which, if any, of the following structures represent meso compounds? (Blue = N, green = Cl.)
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