Chapter 5: Q. 28 E-a (page 148)
Which, if any, of the following structures represent meso compounds? (Blue = N, green = Cl.)
Short Answer
(a). Meso compounds
Chapter 5: Q. 28 E-a (page 148)
Which, if any, of the following structures represent meso compounds? (Blue = N, green = Cl.)
(a). Meso compounds
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Get started for freeOne of the steps in fat metabolism is the hydration of crotonate to yield 3-hydroxybutyrate. This reaction occurs by addition of โOH to the Si face at C3, followed by protonation at C2, also from the Si face. Draw the product of the reaction, showing the stereochemistry of each step.
Which of the following objects are chiral?
(a) A basketball
(b) A fork
(c) A wine glass
(d) A golf club
(e) A spiral staircase
(f) A snowflake
(d)
Ribose, an essential part of ribonucleic acid (RNA), has the following structure:
(a) How many chirality centers does ribose have? Identify them.
(b) How many stereoisomers of ribose are there?
(c) Draw the structure of the enantiomer of ribose.
(d) Draw the structure of a diastereomer of ribose.
Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each:
(a)
(b)
(c)
The dehydration of citrate to yield cis-aconitate, a step in the citric acid cycle, involves the pro-R โarmโ of citrate rather than the pro-S arm. Which of the following two products is formed?
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