Chapter 11: Q47bE (page 350)
Question: Predict the product and give the stereochemistry resulting from reaction of each of the following nucleophiles with (R)-2-bromooctane:
(b)
Short Answer
Answer
Chapter 11: Q47bE (page 350)
Question: Predict the product and give the stereochemistry resulting from reaction of each of the following nucleophiles with (R)-2-bromooctane:
(b)
Answer
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a.
(S)-2-Butanol slowly racemizes on standing in dilute sulfuric acid. Explain.
Question: The reactions shown below are unlikely to occur as written. Tell what is wrong with each, and predict the actual product.
a.
Reaction of iodoethane withyields a small amount of isonitrile,, along with the nitrileas the major product. Write electron-dot structures for both products, assign formal charges as necessary, and propose mechanisms to account for their formation.
Question:What products would you expect from the reaction of 1-bromopropane with each of the following?
(c) NaI
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