Chapter 11: Q.11-50c (page 350)
Question:What products would you expect from the reaction of 1-bromopropane with each of the following?
(c) NaI
Short Answer
Answer
Chapter 11: Q.11-50c (page 350)
Question:What products would you expect from the reaction of 1-bromopropane with each of the following?
(c) NaI
Answer
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Get started for freeTell whether each of the following reactions is likely to be SN1, SN2, E1, E1cB or E2:
c)
Among the many examples of reactions that occur with incomplete racemization, the optically pure tosylate of 2,2-dimethyl-1-phenyl-1-propan(= 230.3) gives the corresponding acetate (= 15.3) when heated inacetic acid. If complete inversion had occurred, the optically pure acetatewould have had= 153.6. What percentage racemization and what percentageinversion occurred in this reaction?
Which reactant in each of the following pairs is more nucleophilic? Explain.
a) BF3 or F-
Question:What products would you expect from the reaction of 1-bromopropane with each of the following?
(e)
Question: There are eight diastereomers of 1,2,3,4,5,6-hexachlorocyclohexane. Draw each in its more stable chair conformation. One isomer loses HCl in an E2 reaction nearly 1000 times more slowly than the others. Which isomer reacts so slowly, and why?
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