Chapter 11: Q 11-11-20-P-c (page 347)
d) Tell whether each of the following reactions is likely to be SN1, SN2, E1, E1cB or E2:
Short Answer
The given reaction is an E1cBreaction
Chapter 11: Q 11-11-20-P-c (page 347)
d) Tell whether each of the following reactions is likely to be SN1, SN2, E1, E1cB or E2:
The given reaction is an E1cBreaction
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Get started for freeSN2 reactions take place with inversion of configuration, andSN1 reactions take place with racemization. The following substitution reaction, however, occurs with complete retention of configuration. Propose a mechanism.
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Question: The reactions shown below are unlikely to occur as written. Tell what is wrong with each, and predict the actual product.
a.
Write the product you would expect from reaction of each of the following alkyl halides with (1)Na+-SCH3and (2)Na+-OH (green = Cl):
c)
What stereochemistry do you expect for the trisubstituted alkene obtained by E2 elimination of the following alkyl halide on treatment with KOH? (Reddish brown = Br.)
Which reactant in each of the following pairs is more nucleophilic? Explain.
b) H2O or CH3CO2-
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