Chapter 11: 45dE (page 350)
How might you prepare each of the following molecules using a nucleophilic substitution reaction at some step?
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Question: Propose structures for compounds that fit the following descriptions:
(b) An organohalide that will not undergo nucleophilic substitution
Question: The reactions shown below are unlikely to occur as written. Tell what is wrong with each, and predict the actual product.
b.
Question: Arrange the carbocations below, in order of increasing stability.
c.
Tell whether each of the following reactions is likely to be SN1, SN2, E1, E1cB or E2:
b)
Reaction of iodoethane withyields a small amount of isonitrile,, along with the nitrileas the major product. Write electron-dot structures for both products, assign formal charges as necessary, and propose mechanisms to account for their formation.
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