Chapter 8: Q8-2P. (page 222)
Question: How many alkene products, including E, Z isomers, might be obtained by dehydration of 3-methyl-3-hexanol with aqueous sulfuric acid?
Short Answer
Answer
The five alkene products formed are,
Chapter 8: Q8-2P. (page 222)
Question: How many alkene products, including E, Z isomers, might be obtained by dehydration of 3-methyl-3-hexanol with aqueous sulfuric acid?
Answer
The five alkene products formed are,
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Get started for freeAn unknown hydrocarbon A with the formula reacts with 1 molar equivalent of over a palladium catalyst. Hydrocarbon A also reacts with to give diol B. When oxidized with in acidic solution, A gives two fragments. One fragment is propanoic acid, , and the other fragment is ketone C. What are the structures of A, B, and C? Write all reactions, and show your reasoning.
Question: In planning the synthesis of one compound from another, itโs just as important to know what not to do as to know what to do. The following reactions all have serious drawbacks to them. Explain the potential problems of each.
Question:Show the structures of alkenes that give the following products on oxidative cleavage with KMnO4 in acidic solution:
c.
Reaction of HBr with 3-methylcyclohexene yields a mixture of four products: cis- and trans-1-bromo-3-methylcyclohexane and cis- and trans-1-bromo-2-methylcyclohexane. The analogous reaction of HBr with 3-bromocyclohexene yields trans-1,2-dibromocyclohexane as the sole product. Draw structures of the possible intermediates, and then explain why only a single product is formed in this reaction.
Question:Predict the products of the following reactions, showing both regiochemistry and stereochemistry where appropriate:
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