Chapter 8: Q70cE. (page 262)
We’ll see in the next chapter that alkynes undergo many of the same reactions that alkenes do. What product might you expect from each of the following reactions?
Chapter 8: Q70cE. (page 262)
We’ll see in the next chapter that alkynes undergo many of the same reactions that alkenes do. What product might you expect from each of the following reactions?
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Get started for freeCompound A, C10H18O, undergoes reaction with dilute H2SO4at 50 °C to yield a mixture of two alkenes, C10H16. The major alkene product, B, gives only cyclopentanone after ozone treatment followed by reduction with zinc in acetic acid. Identify A and B, and write the reactions.
Cyclopentanone
Draw the structure of a hydrocarbon that absorbs 2 molar equivalents of H2 on catalytic hydrogenation and gives only butanedial on ozonolysis.
Butanedial
Question:How would you carry out the following transformations? Tell what
reagents you would use in each case.
(b)
The following alkene undergoes hydroboration–oxidation to yield a single product rather than a mixture. Explain the result, and draw the product showing its stereochemistry.
Question: What product would you expect to obtain from addition of to 1,2-dimethyl-cyclohexene? Show the stereochemistry of the product.
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