Chapter 10: Q8P-b (page 298)
How would you prepare the following alkyl halides from the corresponding alcohols?
Short Answer
The given compound is 2-bromo,4-methylpentane. It can be prepared as the following way:
Chapter 10: Q8P-b (page 298)
How would you prepare the following alkyl halides from the corresponding alcohols?
The given compound is 2-bromo,4-methylpentane. It can be prepared as the following way:
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Get started for freeDraw the electron-pushing mechanism for the propagation steps of the allylic bromination reactions below. You may omit NBS in your mechanism, and use Brโ and Br2.
(b)
Question: The syntheses shown here are unlikely to occur as written. What is
wrong with each?
Reaction 1
Reaction 2
Taking the relative reactivities of 1ยฐ, 2ยฐ, and 3ยฐ hydrogen atoms into account, what product(s) would you expect to obtain from monochlorination of 2-methylbutane? What would the approximate percentage of each product be? (Donโt forget to take into account the number of each kind of hydrogen.)
Draw structures corresponding to the following IUPAC names: (b) 3,3-Dichloro-2-methylhexane.
Question: How strong a base would you expect a Grignard reagent to be? Look at Table 9-1 on page 276, and predict whether the following reactions will occur as written. (The of is 35.)
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