Chapter 10: Q10-33E-b (page 308)
Tell whether each of the following reactions is an oxidation, a reduction, or neither:
Answer
It is neither an oxidation nor reduction reaction.
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The relative rate of radical bromination is 1; 82; 1640 for 1°;2°;3°
hydrogens, respectively. Draw all of the monobrominated products that
you might obtain from the radical bromination of the compounds
below. Calculate the relative percentage of each.
(a)Methylcyclobutane
(b)3,3-dimethylpentane
(c)3-methylpentane
Draw the electron-pushing mechanism for the propagation steps of the allylic bromination reactions below. You may omit NBS in your mechanism, and use Br∙ and Br2.
(b)
How would you prepare the following compounds, starting with cyclopentene and any other reagents needed? (c) 3-Bromocyclopentene.
Draw three resonance forms for the cyclohexadienyl radical.
Cyclohexadienyl radical
Give IUPAC names for the following alkyl halide (e):
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