Chapter 10: Q10-25E-c (page 308)
How would you prepare the following compounds, starting with cyclopentene and any other reagents needed? (c) 3-Bromocyclopentene.
Short Answer
3-Bromocyclopentene can be formed in the following way:
Chapter 10: Q10-25E-c (page 308)
How would you prepare the following compounds, starting with cyclopentene and any other reagents needed? (c) 3-Bromocyclopentene.
3-Bromocyclopentene can be formed in the following way:
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Draw structures corresponding to the following IUPAC names: (c) 3-Bromo-3-ethylpentane.
Question: Why do you suppose it’s not possible to prepare a Grignard reagentfrom a bromo alcohol such as ? Give another exampleof a molecule that is unlikely to form a Grignard reagent.
Alkyl halides can be reduced to alkanes by a radical reaction with tributyltinhydride, in the presence of light (hv). Propose aradical chain mechanism by which the reaction might occur. The initiationstep is the light-induced homolytic cleavage of the Sn-H bondto yield a tributyltin radical.
Draw structures corresponding to the following IUPAC names: (d) 1,1-Dibromo-4-isopropylcyclohexane.
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