Chapter 4: Q4-33E (page 114)
Draw 1, 3, 5-trimethyl cyclohexane using a hexagon to represent the ring. How many cis-trans stereoisomers are possible?
Short Answer
There are two pairs of cis-trans stereoisomers are possible.
Chapter 4: Q4-33E (page 114)
Draw 1, 3, 5-trimethyl cyclohexane using a hexagon to represent the ring. How many cis-trans stereoisomers are possible?
There are two pairs of cis-trans stereoisomers are possible.
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Cis-decalin is less stable than trans-decalin. Assume that the 1,3-diaxial interactions in cis-decalin are similar to those in axial methylcyclohexane [that is, one CH H interaction costs 3.8 kJ/mol (0.9 kcal/mol)], and calculate the magnitude of the energy difference between cis- and trans-decalin.
Which isomer is more stable, cis-decalin or trans-decalin? Explain.
A 1, 2-trans disubstituted cyclohexane must have either both groups axial or both groups equatorial. Explain.
Why is a 1, 3-cis disubstituted cyclohexane more stable than its trans isomer?
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