Chapter 4: Q22 E-a (page 114)
Name the following cycloalkanes:
b. Name the following cycloalkanes:
Short Answer
The name of the compound is
The name of the compound is
Chapter 4: Q22 E-a (page 114)
Name the following cycloalkanes:
b. Name the following cycloalkanes:
The name of the compound is
The name of the compound is
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Get started for freeWhy is a 1, 3-cis disubstituted cyclohexane more stable than its trans isomer?
Why do you suppose an axial cyano (–CN) substituent causes practically no 1,3-diaxial steric strain (0.4 kJ/mol)? Use molecular models to help with your answer.
In light of your answer to Problem 4-48, draw the two chair conformations of 1,1,3-trimethylcyclohexane and estimate the amount of strain energy in each. Which conformation is favored?
Cis-decalin is less stable than trans-decalin. Assume that the 1,3-diaxial interactions in cis-decalin are similar to those in axial methylcyclohexane [that is, one CH H interaction costs 3.8 kJ/mol (0.9 kcal/mol)], and calculate the magnitude of the energy difference between cis- and trans-decalin.
Which isomer is more stable, cis-decalin or trans-decalin? Explain.
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