Chapter 30: Q28E (page 1033)
Predict the product of the following pericyclic reaction. Is this [5,5] shift a suprafacial or an antarafacial process?
Short Answer
The product of the following pericyclic reaction can be predicted.
Chapter 30: Q28E (page 1033)
Predict the product of the following pericyclic reaction. Is this [5,5] shift a suprafacial or an antarafacial process?
The product of the following pericyclic reaction can be predicted.
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Get started for freeThe following reaction is an example of a [2,3] sigmatropic rearrangement. Would you expect the reaction to be suprafacial or antarafacial? Explain.
Propose a pericyclic mechanism to account for the following transformation.
The cyclohexadecaoctaene shown isomerizes to two different isomers, depending on reaction conditions. Explain the observed results, and indicate whether each reaction is conrotatory or disrotatory.
Two sequential pericyclic reactions are involved in the following furan synthesis. Identify them, and propose a mechanism for the transformation.
Look at Figure 30-1, and tell which molecular orbital is the HOMO and whichis the LUMO for both ground and excited states of ethylene and 1,3-butadiene.
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